Synthesis and Structural Characterization of Copper(II) Complex with Asymmetrical Salen-Type Bisoxime Ligand

被引:0
|
作者
Li, Wen-You [1 ]
Zhang, Yu-Jie [2 ]
Dong, Xiu-Yan [2 ]
Li, Xiang [2 ]
Wang, Li [2 ]
机构
[1] Jiuquan Vacat & Tech Coll, Dept Chem Engn, Jiuquan 735009, Peoples R China
[2] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
关键词
Copper(II) complex; Asymmetrical bisoxime ligand; Synthesis; Crystal structure; CRYSTAL-STRUCTURE; CO(II); CD; LN;
D O I
10.14233/ajchem.2013.14687
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new mononuclear Cu(II) complex, [CuL], has been synthesized by the reaction of copper(II) acetate tetrahydrate with H2L (H2L = 4-bromo-6'-methoxy-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol). X-Ray crystallographic analysis reveals that the complex crystallizes in the monoclinic system, space group P2(1) and the unit cell contains two crystallographically independent but chemically identical molecules which interlink each other into a 1D infinite chain through four strong intermolecular O12-H12C center dot center dot center dot O4, O12-H12D center dot center dot center dot O5, O11-H11C center dot center dot center dot O9 and O11-H11D center dot center dot center dot O10 hydrogen bonds.
引用
收藏
页码:5084 / 5086
页数:3
相关论文
共 50 条
  • [21] Copper(II)-Mediated Transformation of a Tridentate Non-Innocent Ligand into a Tetradentate Salen-Type Innocent Ligand
    Ghorai, Samir
    Mukherjee, Chandan
    CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (12) : 3518 - 3524
  • [22] Synthesis and characterization of binuclear Co(II) complexes with bis(salen-type) ligands
    Raisanen, Minna T.
    Korpi, Heikki
    Sundberg, Markku R.
    Savin, Alexander
    Leskela, Markku
    Repo, Timo
    INORGANICA CHIMICA ACTA, 2013, 394 : 203 - 209
  • [23] Synthesis, crystal structure, and properties of supramolecular CuII, ZnII, and CdII complexes with Salen-type bisoxime ligands
    School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China
    Inorg. Chim. Acta, 1600, 1 (117-124):
  • [24] Synthesis and Properties of Salen-Type Ni, Cu, Mn Complexes with Asymmetrical Structure
    Wang Na-Na
    Guo Li-Qin
    Zhang Xiao-Hong
    Ruan Wen-Juan
    Zhu Zhi-Ang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (03) : 445 - 452
  • [25] Synthesis, crystal structure, and properties of supramolecular CuII, ZnII, and CdII complexes with Salen-type bisoxime ligands
    Dong, Wen-Kui
    Sun, Yin-Xia
    Zhang, Yan-Ping
    Li, Li
    He, Xue-Ni
    Tang, Xiao-Lu
    INORGANICA CHIMICA ACTA, 2009, 362 (01) : 117 - 124
  • [26] Synthesis, Structure and Properties of an Erbium(III) Complex with Chiral Salen-type Schiff Base Ligand
    Sui, Yan
    Hu, Rong-Hua
    Luo, Zhi-Gang
    Lin, Wen-Hua
    Liu, Dong-Sheng
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (8-9): : 1566 - 1570
  • [27] Synthesis and characterization of nickel(II), cobalt(II) manganese(II), copper(II), iron(III) and chromium(III) complexes of unsymmetrical salen-type ligand and their application as catalysts for the oxidation of styrene
    Maldhure, Atish K.
    Aswar, Anand S.
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2009, 86 (07) : 697 - 702
  • [28] Synthesis, Structural Characterization, and Chiroptical Studies of Bidentate Salen-Type Lanthanide (III) Complexes
    Berardozzi, Roberto
    Pescitelli, Gennaro
    Di Pietro, Sebastiano
    Resta, Claudio
    Ballistreri, Francesco P.
    Pappalardo, Andrea
    Tomaselli, Gaetano A.
    Di Bari, Lorenzo
    CHIRALITY, 2015, 27 (12) : 857 - 863
  • [29] Synthesis, structure and properties of supramolecular MnII, CoII, NiII and ZnII complexes containing Salen-type bisoxime ligands
    Dong, Wen-Kui
    Sun, Yin-Xia
    Zhao, Chun-Yu
    Dong, Xiu-Yan
    Xu, Li
    POLYHEDRON, 2010, 29 (09) : 2087 - 2097
  • [30] Synthesis, structural characterization and chromotropism of a copper(II) complex containing a bidentate ligand
    Golchoubian, Hamid
    Tarahomi, Mahbobeh
    Rezaee, Ehsan
    Bruno, Giuseppe
    POLYHEDRON, 2015, 85 : 635 - 642