P-chirogenic Trost ligands mediated asymmetric hydrogenation of simple ketones

被引：3
|
作者：
Du, Peng [1 ]
Liu, Yan-Lan [1 ]
Lu, Xiao-Bing [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 42期
关键词：
Asymmetric hydrogenation; P-chirogenic Trost ligands; Simple ketones; Ruthenium; ENANTIOSELECTIVE HYDROGENATION; PHOSPHORUS LIGANDS; ARYL KETONES; CATALYSTS; REDUCTION; COMPLEXES; DIPHOSPHINE; EFFICIENT; ALCOHOLS;
D O I：
10.1016/j.tetlet.2020.152386
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein, we report a highly active catalyst system consisting of (R-c,R-c,R-p,R-p)-P-chirogenic Trost ligand and [Ru(C6H6)Cl-2](2) for asymmetric hydrogenation of simple ketones, affording the corresponding optically active alcohols in moderate enantioselectivity. A synergetic effect between P- and C-chirogenic centers of the P-chirogenic Trost ligands was observed in this asymmetric hydrogenation process. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数：4
相关论文
共 50 条
  • [31] Asymmetric Synthesis of P-Chirogenic Ferrocenyl BiphePFc* Diphosphine by Ephedrine-Aryne Methods and Application in Rhodium-Catalyzed Hydrogenation
    Bayardon, Jerome
    Das, Utpal
    Rousselin, Yoann
    Juge, Sylvain
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (24): : 18733 - 18738
  • [32] Iridium Catalysts with f-Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones
    Wu, Weilong
    Liu, Shaodong
    Duan, Meng
    Tan, Xuefeng
    Chen, Caiyou
    Xie, Yun
    Lan, Yu
    Dong, Xin-Qin
    Zhang, Xumu
    ORGANIC LETTERS, 2016, 18 (12) : 2938 - 2941
  • [33] Asymmetric hydrogenation of simple ketones.
    Zhang, XM
    Jiang, YT
    Wang, B
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U41 - U41
  • [34] Asymmetric hydrogenation of simple ketones.
    Zhang, XM
    Jiang, YT
    Wang, B
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U55 - U55
  • [35] Non-racemic tin(IV) complexes containing P-chirogenic phosphinomethylphenolate ligands
    Müller, G
    Brand, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (13-14): : 2820 - 2829
  • [36] Ir-catalyzed asymmetric hydrogenation of simple ketones with chiral ferrocenyl P,N,N-ligands
    Qin, Chao
    Hou, Chuan-Jin
    Liu, Hongzhu
    Liu, Yan-Jun
    Huang, De-Zhi
    Hu, Xiang-Ping
    TETRAHEDRON LETTERS, 2018, 59 (08) : 719 - 722
  • [37] Efficient Stereoselective Synthesis of o-Functionalized P-Chirogenic Phosphines Applied to Asymmetric Catalysis
    Bayardon, Jerome
    Juge, Sylvain
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2015, 190 (5-6) : 700 - 705
  • [38] Bulky P*-Chirogenic Diazaphospholidines as Monodentate Ligands for Asymmetric Catalysis
    Gavrilov, Konstantin N.
    Benetskiy, Eduard B.
    Grishina, Tatiana B.
    Rastorguev, Eugenie A.
    Maksimova, Marina G.
    Zheglov, Sergey V.
    Davankov, Vadim A.
    Schaeffner, Benjamin
    Boerner, Armin
    Rosset, Stephane
    Bailat, Gaelle
    Alexakis, Alexandre
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (23) : 3923 - 3929
  • [39] Asymmetric transfer hydrogenation of ketones catalyzed by metal complexes with simple amino acid ligands
    Morris, David
    Merola, Joseph S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [40] Novel simple and highly modular ligands for efficient asymmetric transfer-hydrogenation of ketones
    Pastor, IM
    Västilä, P
    Adolfsson, H
    CHEMICAL COMMUNICATIONS, 2002, (18) : 2046 - 2047
12345