Preparation and properties of conductive amorphous mercury tetrathiolato polymers

被引:0
|
作者
Tang, Y [1 ]
Gan, XM [1 ]
Tan, MY [1 ]
机构
[1] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
来源
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 06期
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D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation and properties of two series of polymers based on mercury complexes of ethylenetetrathiolate (ett) and tetrathiafulvalenetetrathiolate ligand (ttftt) of stoichiometry [[(Hg-ett)Lnx](n)(Ln = La, Nd, Sm, Eu, x = 0.4; Ln = Er, Y, x = 0.3) and [(Hg-ttftt)Lyn](n)(Ln = La, Nd, Sm, Eu, Er, Y, y = 0.2) are described. The insoluble amorphobls polymer complexes have been characterized by elemental analysis, IR spectra, TG-DTA techniques and conductivity measurements. As compacted pellets these complexes behave as semi-conductors at 25 degrees C.
引用
收藏
页码:587 / 589
页数:3
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