Determination of the rate constants of the addition of primary alkyl radicals to allylstannanes

被引：0

作者：

Ferkous, F

Degueil-Castaing, M

Deleuze, H

Maillard, B ^{[1
]}

机构：

[1] Univ Bordeaux 1, Chim Organ & Organomet Lab, CNRS, UMR 5802, F-33405 Talence, France

[2] Univ Annaba, Inst Chim, Chim Organ Lab, Annaba, Algeria

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2002年 / 02期

关键词：

D O I：

10.1039/b108875k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rate constants and the activation parameters of the addition of primary alkyl radicals to allyldibutyl-4,7,10-trioxaundecylstannane 1 and (2-ethoxycarbonylprop-2-enyl)dibutyl-4,7,10-trioxaundecylstannane 2 were determined by studying their respective free radical reactions with (2-bromo-1,1-dimethylethyl)benzene and 6-bromohex-1-ene at different temperatures.

引用

页码：247 / 250

页数：4

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