Crystal growth and structure of V2VSe2IVO9;: comparison with V2Te2O9

被引：12
|
作者：
Millet, P
Galy, J
Johnsson, M
机构：
[1] CNRS, Ctr Elaborat Materiaux & Etudes Struct, F-31055 Toulouse 4, France
[2] Univ Stockholm, Dept Inorgan Chem, S-10691 Stockholm, Sweden
来源：
SOLID STATE SCIENCES | 1999年 / 1卷 / 05期
关键词：
D O I：
10.1016/S1293-2558(00)80082-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
High quality single crystals of V2Se2O9 have been obtained as a side compound during a study of the CuCl2-V2O5-SeO2 system. V2Se2O9 crystallises in the monoclinic system, space group P2(1)/n with a = 8.0560(2), b = 10.3650(2), c = 8.4500(2) Angstrom, beta = 102.893(2)degrees, Z = 4 and, rho(x) = 3.90 g/cm(3). Full matrix least-squares refinement gave an R = 0.0347 and R-w = 0.0802 using 2232 independent reflections. The structure is built up by very distorted octahedra occupied by V5+ sharing one edge and one apex to form [V4O18](16-). entities interconnected by SeO3E tetrahedra (E designs the 4s(2) lone pair of the Se (IV) cation). V2Se2O9 is not isostructural with V2Te2O9, in which the V5+O6 octahedra share edges to form along [011] infinite chains linked together via Te2O5E2 groups.
引用
收藏
页码：279 / 286
页数：8
相关论文
共 50 条
  • [31] Structure and polymorphism of the La2Mo2O9 compounds, doped with Bi, Sb and V
    Alekseeva, Olga
    Sorokina, Natalya
    Novikova, Natalya
    Gagor, Anna
    Pietraszko, Adam
    Kharitonova, Elena
    Voronkova, Valentina
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C713 - C713
  • [32] MgBi2V2O9: preparation and electrical property evaluation
    P. L. Deepti
    S. K. Patri
    R. N. P. Choudhary
    Journal of Materials Science: Materials in Electronics, 2017, 28 : 16071 - 16076
  • [33] MgBi2V2O9: preparation and electrical property evaluation
    Deepti, P. L.
    Patri, S. K.
    Choudhary, R. N. P.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (21) : 16071 - 16076
  • [34] Dielectric properties of the low dimensional vanadium oxides Ba2V3O9 and Sr2V3O9
    Bobnar, V
    Lunkenheimer, P
    Loidl, A
    Kaul, EE
    Geibel, C
    SOLID STATE COMMUNICATIONS, 2002, 122 (11) : 595 - 599
  • [35] Hydrothermal synthesis and crystal structure of a novel compound:: [Ni(phen)3]2[SiMo10V2IVO40(VIVO)2]•2H2O
    Luan, GY
    Li, YG
    Wang, EB
    Han, ZB
    Hu, CW
    Hu, NH
    Jia, HQ
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (07) : 509 - 511
  • [36] On the Polymorphism of Cu2V2O7: Synthesis and Crystal Structure of δ-Cu2V2O7, a New Polymorph
    Kornyakov, Ilya V.
    Krivovichev, Sergey V.
    CRYSTALS, 2024, 14 (10)
  • [37] SYNTHESIS AND CRYSTAL-STRUCTURE OF MN4NB2O9 AND MN2ZN2NB2O9
    ROHWEDER, U
    MULLERBUSCHBAUM, H
    JOURNAL OF THE LESS-COMMON METALS, 1988, 138 (01): : 79 - 86
  • [38] The crystal structure of KNa3Te8O18•5H2O exhibiting a ∞2[Te4O9]2- layer
    Geng, Lei
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2022, 237 (01): : 179 - 181
  • [39] DOUBLE-OCTAHEDRA CLUSTERS [V2O9] IN THE CRYSTAL-STRUCTURE OF VANADIUM(III) DIPHOSPHATE, V4(P2O7)3
    PALKINA, KK
    MAKSIMOVA, SI
    CHIBISKOVA, NT
    SCHLESINGER, K
    LADWIG, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 529 (10): : 89 - 96
  • [40] CRYSTAL-STRUCTURE OF BISPHENOXATELLURONIUM DINITRATE, C24H16O9N2TE2
    MANGION, MM
    SMITH, MR
    MYERS, EA
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1973, 10 (04) : 543 - 549
12345