Electrospun chitosan/PEDOT nanofibers

被引:34
|
作者
Kiristi, Melek [1 ]
Oksuz, Aysegul Uygun [1 ]
Oksuz, Lutfi [2 ]
Ulusoy, Seyhan [3 ]
机构
[1] Suleyman Demirel Univ, Arts & Sci Fac, Dept Chem, TR-32260 Isparta, Turkey
[2] Suleyman Demirel Univ, Arts & Sci Fac, Dept Phys, TR-32260 Isparta, Turkey
[3] Suleyman Demirel Univ, Arts & Sci Fac, Dept Biol, TR-32260 Isparta, Turkey
关键词
Plasma-modification; Chitosan; Electrospinning; Poly(3,4-ethylenedioxythiophene); Antibacterial; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); MORPHOLOGY; FABRICATION; 3,4-ETHYLENEDIOXYTHIOPHENE; POLYMERIZATION; NANOTUBES; MEMBRANES;
D O I
10.1016/j.msec.2013.05.018
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
Plasma-modified chitosan and poly(3,4-ethylenedioxythiophene) were blended to obtain conducting nanofibers with polyvinyl alcohol as a supporting polymer at various volumetric ratios by electrospinning method. Chemical compositions and molecular interactions among nanofiber blend components were determined using Fourier transform infrared spectroscopy (FTIR). The conducting blends containing plasma-modified chitosan resulted in a superior antibacterial activity and thinner fiber formation than those containing chitosan without plasma-modification. The obtained nanofiber diameters of plasma-modified chitosan were in the range of 170 to 200 nm and those obtained from unmodified chitosan were in the range of 190 to 246 nm. The electrical and electrochemical properties of nanofibers were also investigated by four-point probe conductivity and cyclic voltammetry measurements. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:3845 / 3850
页数:6
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