This chapter provides an introduction to a certain class of nonlinear electrokinetic phenomena, where the applied electric field acts on its own induced,charge in an electrolytic solution near a polarizable surface. Many applications are discussed, such as colloidal particle dynamics (induced-charge electrophoresis) and microfluidic mixing and pumping (induced-charge electro-osmosis), while emphasizing the basic physics of each phenomenon. A Standard Model for these situations is introduced and analyzed in simple cases. Similarities and differences are noted with other electrokinetic phenomena, such as classical linear (fixed-charge) electrokinetics in electrolytes and electrohydrodynamics in leaky dielectrics.
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Argonne Natl Lab, Biosci Div, Argonne, IL 60439 USA
Rush Univ, Med Ctr, Dept Mol Biophys & Physiol, Chicago, IL 60612 USAArgonne Natl Lab, Biosci Div, Argonne, IL 60439 USA
Bardhan, Jaydeep P.
Eisenberg, Robert S.
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Rush Univ, Med Ctr, Dept Mol Biophys & Physiol, Chicago, IL 60612 USA
Argonne Natl Lab, Math & Comp Sci Div, Argonne, IL 60439 USAArgonne Natl Lab, Biosci Div, Argonne, IL 60439 USA
Eisenberg, Robert S.
Gillespie, Dirk
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Rush Univ, Med Ctr, Dept Mol Biophys & Physiol, Chicago, IL 60612 USAArgonne Natl Lab, Biosci Div, Argonne, IL 60439 USA