Crystal structure of hydrazone form of 1-butyl-3-cyano-6-hydroxy-4-methyl-5-(2-thiazolylazo)-2-(1H)-pyridone

被引：8

作者：

Temel, A

Ozbey, S

Ertan, N

机构：

[1] HACETTEPE UNIV,DEPT ENGN PHYS,TR-06532 BEYTEPE,ANKARA,TURKEY

[2] GAZI UNIV,ART & SCI FAC,DEPT CHEM,TR-06403 ANKARA,TURKEY

来源：

DYES AND PIGMENTS | 1996年 / 32卷 / 04期

关键词：

D O I：

10.1016/S0143-7208(96)00028-9

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The structural results clearly indicate that 1-butyl-3-cyano-6-hydroxy-4-methyl-5-(2-thiazolylazo)-2(1H)-pyridone, (C14H15N5O2S) exists primarily as the hydrazone tautomer in the solid state. The molecule is nearly planar not regarding the butyl group. Some of the bond lengths and angles are distorted due to pi-electron delocalization and strain. A strong intramolecular N-H ... O hydrogen bond was found [N ... O = 2.53(1)Angstrom]. The crystallographic parameters are as follows: triclinic <P(1)over bar>, a = 5.972(4)Angstrom, b = 7.732(5)Angstrom, c = 17.348 (9) Angstrom, alpha = 85.62(5)degrees, beta = 79.24(6)degrees, gamma = 78.41(7)degrees, V = 770.4(9)Angstrom(3) Z=2, D-c = 1.37 g cm(-3), mu(MoKalpha) = 2.1 cm(-1), R = 0.045, G.O.F. = 1.78. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：237 / 244

页数：8

共 50 条

[21] STUDIES ON PROTOTROPIC TAUTOMERISM IN NITROGENHETEROCYCLIC COMPOUNDS .2. A RING-CHAIN-TAUTOMERISM IN 3-HYDROXY-6-(2-OXOCYCLOALKYL)-METHYL-2(1H)-PYRIDONE AND 3-HYDROXY-6-(3-OXOALKYL)-2(1H)-PYRIDONE DERIVATIVES
NAKAMURA, A
KAMIYA, S
CHEMICAL & PHARMACEUTICAL BULLETIN, 1969, 17 (03) : 425 - +
[22] Synthesis and transformations of 4-methyl-6-methoxymethyl-3-cyano-2(1H)-pyridinethione
Kaigorodova, EA
Konyushkin, LD
Mikhailichenko, SN
Vasilin, VK
Sazonov, AV
Kulnevich, VG
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1999, (03): : 337 - 341
[23] Synthesis and reactions of 3-cyano-6-methoxymethyl-4-methyl-2(1H)-pyridinethione
Kaigorodova E.A.
Konyushkin L.D.
Mikhailichenko S.N.
Vasilin V.K.
Sazonov A.V.
Kul'nevich V.G.
Chemistry of Heterocyclic Compounds, 1999, 35 (3) : 293 - 296
[24] 4-Hydroxy-1-methyl-3-phenylquinolin-2(1H)-one
Kafka, Stanislav
Pevec, Andrej
Proisl, Karel
Kimmel, Roman
Kosmrlj, Janez
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O231 - +
[25] Synthesis, Crystal Structure and Antibacterial Activities of 3-[(2-Hydroxy-4-diethylamino-phenyl)methylenehydrazinocarbonyl]-4-hydroxy-6-methyl-2(1H)-pyridinones
LI Fanga PAN FuYoua YANG JianGuob GE ChangHuaa a Department of Chemistry Taizhou University Zhejiang China bOffice of Assets Administration Taizhou University Zhejiang China
结构化学, 2006, (05) : 626 - 630
[26] Synthesis, Crystal Structure and Antibacterial Activities of 3-[(2-Hydroxy-4-diethylamino-phenyl)methylenehydrazinocarbonyl]-4-hydroxy-6-methyl-2(1H)-pyridinones
LI Fanga PAN Fu-Youa② YANG Jian-Guob GE Chang-Huaa a (Department of Chemistry
Chinese Journal of Structural Chemistry, 2006, (05) : 626 - 630
[27] Crystal structure of 3-cyano-4-(4-chlorophenyl)-5,6-dimethyl-2(1H)-pyridone, C14H,11CIN2O
Balalaie, Saeed
Hashemi, Mohammed M.
Khezri, Seyed H.
Rominger, Frank
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (01): : 23 - 26
[28] Synthesis of 4-methyl-6-phenyl-3-cyano-5-ethoxycarbonylpyridine-2(1H)-thione and its alkylation
Krivokolysko, SG
Dyachenko, VD
Litvinov, VP
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1999, (12): : 1645 - 1646
[29] 3-CYANO-6-METHYL-2(1)-PYRIDONE - NICOTINONITRILE, 1,2-DIHYDRO-6-METHYL-2-OXO
MARIELLA, RP
ORGANIC SYNTHESES, 1952, 32 : 32 - 34
[30] Synthesis of 3-cyano-5-ethoxycarbonyl-4-methyl-6-phenylpyridine-2(1H)-thione and its alkylation
Krivokolysko S.G.
Dyachenko V.D.
Litvinov V.P.
Chemistry of Heterocyclic Compounds, 1999, 35 (12) : 1441 - 1442

← 1 2 3 4 5 →