One-Pot Sequential Synthesis of Ethers from an Aliphatic Carboxylic Acid and an Alcohol by Indium-Catalyzed Deoxygenation of an Ester

被引：22
|
作者：
Sakai, Norio [1 ]
Usui, Yuta [1 ]
Moriya, Toshimitsu [1 ]
Ikeda, Reiko [1 ]
Konakahara, Takeo [1 ]
机构：
[1] Tokyo Univ Sci, RIKADAI, Fac Sci & Technol, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 2012卷 / 24期
关键词：
Indium; Reduction; Silanes; Ethers; Esters; REDUCTIVE DEOXYGENATION; CARBONYL-COMPOUNDS; SELECTIVE REDUCTION; SYMMETRICAL ETHERS; CONVERSION; ESTERIFICATION; CONDENSATION; LACTONES; HYDRIDE; KETONES;
D O I：
10.1002/ejoc.201200552
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have developed a widely applicable and direct method of etherification from a carboxylic acid and an alcohol by indium-catalyzed deoxygenation of the transient ester formed in a one-pot reaction. This simple catalytic reducing system appears to be remarkably tolerant of several functional groups including alkenes, halogens, nitro and heterocyclic groups.
引用
收藏
页码：4603 / 4608
页数：6
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