Influence of tetragonality and secondary phase on the Curie temperature for barium titanate ceramics

被引:11
|
作者
Tang, Bin [1 ]
Zhang, Shu-Ren [1 ]
Yuan, Ying [1 ]
Yang, Lin-Bo [1 ]
Zhou, Xiao-Hua [1 ]
机构
[1] Univ Elect Sci & Technol China, State Key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Peoples R China
关键词
D O I
10.1007/s10854-007-9477-0
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The effects of tetragonality and secondary phase on the Curie point of barium titanate (BaTiO3) ceramics were investigated in BaTiO3-MnNb2O6 system using differential scanning calorimetry (DSC), X-ray diffraction (XRD) and scanning electron microscope (SEM). In the case of MnNb2O6 addition up to 0.50 mol%, the Curie point decreased as the room temperature tetragonality decreased. With MnNb2O6 content greater than 1.00 mol%, a secondary phase Ba2Ti3Nb4O18 was formed, resulting in a shift of the Curie point towards higher temperatures. The chemical defect reaction and the internal stress effect on the Curie point have also been discussed.
引用
收藏
页码:1109 / 1113
页数:5
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