Coal tar pitch-based porous carbon by one dimensional nano-sized MgO template

被引:25
|
作者
Zhang, Wenfeng [1 ,2 ]
Huang, Zheng-Hong [1 ]
Cao, Gaoping [2 ]
Kang, Feiyu [1 ]
Yang, Yusheng [2 ]
机构
[1] Tsinghua Univ, Dept Mat Sci & Engn, Adv Mat Lab, Beijing 100084, Peoples R China
[2] Res Inst Chem Def, Beijing 100191, Peoples R China
关键词
Amorphous materials; Nanostructures; Chemical synthesis; Electrochemical properties; PORE-SIZE; PERFORMANCE; CAPACITORS;
D O I
10.1016/j.jpcs.2011.11.017
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous carbons are derived by carbonizing coal tar pitch with one dimension non-silica template (needle-like nano-sized MgO). The samples are characterized by nitrogen adsorption at 77 K and XRD analysis. The electrochemical performances for supercapacitor are evaluated in a 6 M KOH aqueous solution. The results show that the as-prepared porous carbons possess abundant mesopores of 3.7-6.5 nm. With air stabilization process, the samples possess more micropores, contributing nearly 50% of surface areas. The porous carbon with large template content through air stabilization possess a high surface area of 864 m(2) g(-1). For supercapacitors electrode material, the porous carbon shows a high capacity and excellent power performance, retaining 100 F g(-1) even at a current density of 30 A g(-1). (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1428 / 1431
页数:4
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