Application of Iridium(III) Complexes in Phosphorescent Chemosensors

被引:2
|
作者
Guo Yuan-Hui
Mei Qun-Bo [1 ]
Yan Fang
Wang Ling-Xia
Weng Jie-Na
Zhang Bin
Huang Wei [1 ]
机构
[1] Nanjing Univ Posts & Telecommun, Key Lab Organ Elect & Informat Displays, Nanjing 210046, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Chemosensor; Charged iridium complex; Neutral iridium complex; Phosphorescence; Energy transfer; CYCLOMETALATED IRIDIUM(III); ELECTROCHEMICAL PROPERTIES; POLYPYRIDINE COMPLEXES; ELECTRON-TRANSFER; DUAL EMISSION; ION-BINDING; LUMINESCENT; SENSOR; DESIGN; PROBE;
D O I
10.3866/PKU.WHXB201112222
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chemosensors have developed quickly because they are widely used in biology. Compared to organic fluorescent chemosensors, phosphorescent chemosensors based on heavy metal complexes have attracted great attention because of distinctive merits such as relatively long lifetimes and significant Stokes shifts. Iridium complexes had been successfully used as phosphorescent chemosensors because of their relatively short excited state lifetime, high photoluminescence efficiency, and wide range emission colors that can be tuned by the coordinated ligands. In this review, we have summarized the applications of iridium complexes in cation, anion, oxygen, amino acid, and pH sensors. Furthermore, the advantages and disadvantages of these chemosensors have been compared to others. Finally, some prospects for future study are proposed.
引用
收藏
页码:739 / 750
页数:12
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共 98 条
  • [31] Probing Pb2+ cation via the iridium based phosphorescent dye
    Ho, Mei-Lin
    Cheng, Yi-Ming
    Wu, Lai-Chin
    Chou, Pi-Tai
    Lee, Gene-Hsiang
    Hsu, Fang-Chi
    Chi, Yun
    [J]. POLYHEDRON, 2007, 26 (17) : 4886 - 4892
  • [32] Design and synthesis of iridium(III) azacrown complex: application as a highly sensitive metal cation phosphorescence sensor
    Ho, ML
    Hwang, FM
    Chen, PN
    Hu, YH
    Cheng, YM
    Chen, KS
    Lee, GH
    Chi, Y
    Chou, PT
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (01) : 98 - 103
  • [33] Colorimetric Detection of Thiols Using a Chromene Molecule
    Huo, Fang-Jun
    Sun, Yuan-Qiang
    Su, Jing
    Chao, Jian-Bin
    Zhi, Hai-Juan
    Yin, Cai-Xia
    [J]. ORGANIC LETTERS, 2009, 11 (21) : 4918 - 4921
  • [34] Evaluation of phosphorescent rhenium and iridium complexes in polythionylphosphazene films for oxygen sensor applications
    Huynh, L
    Wang, ZU
    Yang, J
    Stoeva, V
    Lough, A
    Manners, I
    Winnik, MA
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (19) : 4765 - 4773
  • [35] DUAL EMISSION FROM AN ORTHO-METALATED IR(III) COMPLEX
    KING, KA
    WATTS, RJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (05) : 1589 - 1590
  • [36] Photochemistry and photophysics of coordination compounds: Rhenium
    Kirgan, Robert A.
    Sullivan, B. Patrick
    Rillema, D. Paul
    [J]. PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS II, 2007, 281 : 45 - 100
  • [37] Directed assembly metallocyclic supramolecular systems for molecular recognition and chemical sensing
    Kumar, Arvind
    Sun, Shih-Sheng
    Lees, Alistair J.
    [J]. COORDINATION CHEMISTRY REVIEWS, 2008, 252 (8-9) : 922 - 939
  • [38] Phosphorescent Thymidine Triphosphate Sensor Based on a Donor-Acceptor Ensemble System using Intermolecular Energy Transfer
    Kwon, Tae-Hyuk
    Kim, Hee Jin
    Hong, Jong-In
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (31) : 9613 - 9619
  • [39] Luminescent cyclometallated iridium(III) bis(quinolylbenzaldehyde) diimine complexes-synthesis, photophysics, electrochemistry, protein cross-linking properties, cytotoxicity and cellular uptake
    Lee, Pui-Kei
    Liu, Hua-Wei
    Yiu, Shek-Man
    Louie, Man-Wai
    Lo, Kenneth Kam-Wing
    [J]. DALTON TRANSACTIONS, 2011, 40 (10) : 2180 - 2189
  • [40] Design of Luminescent Biotinylation Reagents Derived from Cyclometalated Iridium(III) and Rhodium(III) Bis(pyridylbenzaldehyde) Complexes
    Leung, Siu-Kit
    Kwok, Karen Ying
    Zhang, Kenneth Yin
    Lo, Kenneth Kam-Wing
    [J]. INORGANIC CHEMISTRY, 2010, 49 (11) : 4984 - 4995