Synthesis of tris(t-butylisocyanide)bis(tri-n-butylphosphine)cobalt(II) perchlorate.: An example of a cobalt(II) complex with alkylisocyanide and trialkylphosphine ligands

被引：0

作者：

Becker, CAL ^{[1
]}

Samarakkody, N ^{[1
]}

机构：

[1] Univ Botswana, Dept Chem, Gaborone, Botswana

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1999年 / 29卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cobalt(II) complex with alkylisocyanide and trialkylphosphine ligands is reported. Tris(t-butylisocyanide)bis(tri-n-butylphosphine)cobalt(II) perchlorate, [Co(CNCMe3)(3){P(C4H9-n)(3)}(2)](ClO4)(2), was synthesized by AgClO4 oxidation of [Co(CNCMe3)(3){P(C4H9-n)(3)}(2)]ClO4. Characterization in solid and solution states indicates that the coordination structure cannot be the familiar axially-disubstituted trigonal bipyramidal coordination seen in eo(II)-triarylphosphine complexes. A C-2v trigonal bipyramidal or square pyramidal structure is postulated for the solution state.

引用

页码：1111 / 1122

页数：12

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