Synthesis and characterization of novel vinyl polymers containing thioester group in side chain

被引：0
|
作者：
Lee, YK [1 ]
Onimura, K [1 ]
Tsutsumi, H [1 ]
Oishi, T [1 ]
机构：
[1] Yamaguchi Univ, Dept Chem Engn & Appl Chem, Yamaguchi 7558611, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1999年 / 37卷 / 20期
关键词：
radical polymerization; 3-mercaptopropionic acid; styrene; methyl methacrylate; N-cyclohexyl maleimide; glass transition temperature; thioester; optical active polymer;
D O I：
10.1002/(SICI)1099-0518(19991015)37:20<3871::AID-POLA16>3.0.CO;2-P
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Three types of new vinyl monomers, methoxycarbonylethyl thioacrylate (MTA), methoxycarbonylethyl thiomethacrylate (MTM), and methoxycarbonylethyl thiomethacrylate (MnTM), all containing a thioester group in the side chain were synthesized. The monomers were homopolymerized and copolymerized with styrene (St), methyl methacrylate (MMA), or N-cyclohexyl maleimide (CHMI). It was found that byreactions of the thioester groups in the polymerization could not occur. All obtained polymers exhibited only amorphous structures.
引用
收藏
页码：3871 / 3875
页数：5
相关论文
共 50 条
  • [31] Polymers containing sulfur in the side chain
    Kultys, A
    Podkoscielny, W
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 61 (10) : 1781 - 1788
  • [32] Alkyne metathesis with simple catalyst systems: Efficient synthesis of conjugated polymers containing vinyl groups in main or side chain
    Brizius, G
    Pschirer, NG
    Steffen, W
    Stitzer, K
    zur Loye, HC
    Bunz, UHF
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (50) : 12435 - 12440
  • [33] Novel properties of conducting polymers containing azobenzene moieties in side chain
    Matsui, T
    Nagata, T
    Ozaki, M
    Fujii, A
    Onoda, M
    Teraguchi, M
    Masuda, T
    Yoshino, K
    SYNTHETIC METALS, 2001, 119 (1-3) : 599 - 600
  • [34] Synthesis and characterization of side-chain liquid crystalline polysiloxanes containing α-terpineol in Inesogenic group
    Mishra, Garima
    Srivastava, A. K.
    DESIGNED MONOMERS AND POLYMERS, 2007, 10 (01) : 37 - 48
  • [35] Synthesis and characterization of side chain polymer with helical PLLA segments containing mesogenic end group
    Chen, Hongru
    Xue, Qingbin
    Li, Zhuohua
    Sun, Lingmin
    Zhang, Quanxuan
    POLYMER, 2011, 52 (02) : 400 - 408
  • [36] Synthesis and characterization of novel side-chain nonlinear optical polymers with furan derivative as an acceptor
    Kaneko, A
    Okamoto, E
    Kaino, T
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2002, 41 (5B): : L559 - L561
  • [37] A novel synthesis of O-phosphorylated amino acids containing hydroxy side chain group
    Zhang, JC
    Cao, SX
    Chen, XL
    Chen, L
    Zhao, YF
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2004, 24 (06) : 650 - 653
  • [38] SYNTHESIS AND CHARACTERIZATION OF LIQUID-CRYSTALLINE MONOMERS AND SIDE-CHAIN POLYMERS CONTAINING DIPHENYLDIACETYLENE MESOGENS
    LU, YH
    HSU, CS
    WU, ST
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1993, 225 : 1 - &
  • [39] Methacrylic polymers containing optically active side-chain carbazole: Synthesis, characterization and photoconductive properties
    Angiolini, Luigi
    Benelli, Tiziana
    Giorgini, Loris
    Golemme, Attilio
    Mauriello, Francesco
    Salatelli, Elisabetta
    Termine, Roberto
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (09) : 944 - 956
  • [40] Synthesis and characterization of halogen-containing ferroelectric liquid crystals and side chain liquid crystalline polymers
    Hsiue, GH
    Sha, YA
    Hsieh, SJ
    Jeng, RJ
    Kuo, WJ
    LIQUID CRYSTALS, 2001, 28 (03) : 365 - 374
12345