Visible-light-promoted Dearomatization of Benzene and Derivatives

被引：11
|
作者：
Zhu, Min [1 ,2 ]
Zhang, Xiao [1 ]
You, Shuli [1 ,2 ]
机构：
[1] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
[2] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2020年 / 41卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Benzene; Dearomatization; Energy transfer; Single electron transfer; Visible light; CATALYTIC ASYMMETRIC DEAROMATIZATION; ORGANIC-PHOTOCHEMISTRY;
D O I：
10.7503/cjcu20200205
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benzene rings are widely found in petrochemicals , which are cheap and readily available. Compared with other ( hetero) aromatic rings , the dearomatization of benzene rings is more challenging as benzene is more stable. On the other hand, visible-light photocatalysis has experienced rapid development since last decade. Upon visible-light irradiation, highly active intermediates are formed to break aromatic stability and to construct three-dimensional molecules from flat compounds. In this review, recent examples on visible-lightpromoted dearomatization of benzene and derivatives are summarized , which can be divided into two main categories : ground-state chemistry and excited-state chemistry. The perspective for future development of this field is also discussed.
引用
收藏
页码：1407 / 1414
页数：8
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