All-Inorganic Single-Ion Magnets in Ceramic Matrices

被引:18
|
作者
Zykin, Mikhail A. [1 ]
Kazin, Pavel E. [1 ]
Jansen, Martin [2 ]
机构
[1] Lomonosov Moscow State Univ, Dept Chem, Leninskie Gory 1, Moscow 119991, Russia
[2] Max Planck Inst Solid State Res, Heisenbergstr 1, D-70569 Stuttgart, Germany
基金
俄罗斯科学基金会;
关键词
magnetic properties; magnetic relaxation; materials science; single-ion magnets; solid state; HIGH-ENERGY BARRIER; MOLECULE MAGNETS; CRYSTAL-STRUCTURE; PHOSPHATE APATITE; MAGNETIZATION; ANISOTROPY; 3D; RELAXATION; EXCHANGE; BEHAVIOR;
D O I
10.1002/chem.201905290
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
All-inorganic single-ion magnets representing paramagnetic ions incorporated in a crystalline diamagnetic matrix are reviewed. Key results and advantages of this approach in comparison with the common strategy based on molecular metal-organic complexes are considered, and some unsolved problems and future perspectives are discussed.
引用
收藏
页码:8834 / 8844
页数:11
相关论文
共 50 条
  • [41] Structurally modulated single-ion magnets of mononuclear β-diketone dysprosium(III) complexes
    Kong, Ming
    Feng, Xin
    Li, Jing
    Hu, Zhao-Bo
    Wang, Jia
    Song, Xiao-Jiao
    Jing, Zhao-Yang
    Zhang, Yi-Quan
    Song, You
    DALTON TRANSACTIONS, 2020, 49 (42) : 14931 - 14940
  • [42] Influence of Inorganic Glass Ceramic Particles on Ion States and Ion Transport in Composite Single-Ion Conducting Gel Polymer Electrolytes with Varying Chain Chemistry
    Doyle, Emily S.
    Ford, Hunter O.
    Webster, David N.
    Giannini, Peter J.
    Tighe, Meghanne E.
    Bartsch, Robert
    Peaslee, Graham F.
    Schaefer, Jennifer L.
    ACS APPLIED POLYMER MATERIALS, 2022, 4 (02) : 1095 - 1109
  • [43] Magnetic Anisotropy and Mechanism of Magnetic Relaxation in Er(III) Single-Ion Magnets
    Singh, Saurabh Kumar
    Gupta, Tulika
    Rajaraman, Gopalan
    INORGANIC CHEMISTRY, 2014, 53 (20) : 10835 - 10845
  • [44] ENERGY EXCITATIONS IN 3-AXIAL MAGNETS WITH SINGLE-ION AND EXCHANGE ANISOTROPIES
    OLEKSY, C
    PRZYSTAWA, J
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1990, 89 (03) : 358 - 368
  • [45] Flexible All-Inorganic Thermoelectric Yarns
    Jang, Hanhwi
    Ahn, Junseong
    Jeong, Yongrok
    Ha, Ji-Hwan
    Jeong, Jun-Ho
    Oh, Min-Wook
    Park, Inkyu
    Jung, Yeon Sik
    ADVANCED MATERIALS, 2024, 36 (47)
  • [46] Role of the Diamagnetic Zinc(II) Ion in Determining the Electronic Structure of Lanthanide Single-Ion Magnets
    Upadhyay, Apoorva
    Das, Chinmoy
    Vaidya, Shefali
    Singh, Saurabh Kumar
    Gupta, Tulika
    Mondol, Ranajit
    Langley, Stuart K.
    Murray, Keith S.
    Rajaraman, Gopalan
    Shanmugam, Maheswaran
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (20) : 4903 - 4916
  • [47] Molecular Anisotropy Analysis of Single-Ion Magnets Using an Effective Electrostatic Model
    Baldovi, Jose J.
    Clemente-Juan, Juan M.
    Coronado, Eugenio
    Gaita-Arino, Alejandro
    INORGANIC CHEMISTRY, 2014, 53 (20) : 11323 - 11327
  • [48] Magnetic properties of two coordination isomeric cobalt(II) single-ion magnets
    Cui, Hui-Hui
    Xu, Hong-Juan
    Zhang, Tengkun
    Luo, Shuchang
    Tong, Wei
    Wang, Miao
    Wang, Jin
    Chen, Lei
    Tang, Yanfeng
    DALTON TRANSACTIONS, 2023, 52 (22) : 7718 - 7723
  • [49] Effect of the capping ligand on luminescent erbium(III) β-diketonate single-ion magnets
    Silva, M. Ramos
    Martin-Ramos, P.
    Coutinho, J. T.
    Pereira, L. C. J.
    Martin-Gil, J.
    DALTON TRANSACTIONS, 2014, 43 (18) : 6752 - 6761
  • [50] Capping Ligand Perturbed Slow Magnetic Relaxation in Dysprosium Single-Ion Magnets
    Bi, Ye
    Guo, Yun-Nan
    Zhao, Lang
    Guo, Yang
    Lin, Shuang-Yan
    Jiang, Shang-Da
    Tang, Jinkui
    Wang, Bing-Wu
    Gao, Song
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (44) : 12476 - 12481