A general synthetic route towards soluble poly(1,3-dithienylisothianaphthene) derivatives

被引：10

作者：

Vangeneugden, DL ^{[1
]}

Kiebooms, RHL ^{[1
]}

Vanderzande, DJM ^{[1
]}

Gelan, JMJV ^{[1
]}

机构：

[1] Limburgs Univ Ctr, Div Organ & Polymer Chem, Mat Res Inst, B-3590 Diepenbeek, Belgium

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

关键词：

low-bandgap conjugated polymers; heterocycle synthesis; UV-vis-NIR absorption;

D O I：

10.1016/S0379-6779(98)01315-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

'Formal' copolymers consisting of bithiophene and aromatic isothianaphthene units, based on 1,3-dithienylisothianaphthene (DTI) derivatives, have been synthesized. The obtained materials have low band gaps and show high intrinsic conductivities. The polymers are obtained after oxidative polymerization of the corresponding DTI monomers with FeCl3. Solubilizing alkyl and thioalkyl side chains where introduced on different locations of the DTI skeleton. The substituents also influence the stability of the DTI monomers and the band gap of the polymers.

引用

页码：120 / 121

页数：2

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