Extraction of boron with diols in petroleum benzine and n-amyl alcohol

被引:0
|
作者
Ozay, P [1 ]
Yurdakoc, M [1 ]
Karakaplan, M [1 ]
Hosgören, H [1 ]
机构
[1] Dokuz Eylul Univ, Dept Chem, Fac Arts & Sci, TR-35160 Buca Izmir, Turkey
关键词
boron; diols; extraction; benzine; n-amyl alcohol;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present work, the solvent extraction of boron with 2-ethyl-1,3-hexanediol (EHD), 1,2-dihydroxy-4-oxadodecane (DHD) and 3-(4-tert-butylphenoxy)-1,2-propanediol (BFPD) in petroleum benzine and n-amyl alcohol was thoroughly studied as a function of equilibrium pH. The pH(0.5) values for EHD, DHD and BFPD were determined from R %-pH graphs as 8.3, 2.7 and 2.3 in n-amyl alcohol, respectively. The extraction efficiencies of these diols were also comparatively investigated. The extraction efficiency in both solvents for each extractant was ranged from 78 to 98%. Stripping of boron was achieved as 96% for EHD with NaOH and 81% for BFPD with H2SO4.
引用
收藏
页码:1277 / 1284
页数:8
相关论文
共 50 条
  • [21] Solubility in the system acetic acid -n-amyl alcohol -n-amyl acetate - Water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure
    Trofimova, Maya
    Misikov, Georgii
    Samarov, Artemiy
    Prikhodko, Igor
    Toikka, Maria
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 161 (161):
  • [22] Kinetics of esterification of propionic acid with n-amyl alcohol in the presence of cation exchange resins
    Erdem, Beyhan
    Cebe, Mustafa
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2006, 23 (06) : 896 - 901
  • [23] Isomerization during the preparation of n-amyl chloride
    Whitmore, FC
    Karnatz, FA
    Popkin, AH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 : 2540 - 2542
  • [24] The action of potassium n-amyl xanthate on chalcocite
    Gaudin, AM
    Schuhmann, R
    JOURNAL OF PHYSICAL CHEMISTRY, 1936, 40 (02): : 257 - 275
  • [25] Kinetics of esterification of acetic acid with n-amyl alcohol in the presence of Amberlyst-36
    Akbay, Elif Odes
    Altiokka, Mehmet R.
    APPLIED CATALYSIS A-GENERAL, 2011, 396 (1-2) : 14 - 19
  • [26] Kinetics of esterification of propionic acid with n-amyl alcohol in the presence of cation exchange resins
    Beyhan Erdem
    Mustafa Cebe
    Korean Journal of Chemical Engineering, 2006, 23
  • [27] Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid - n-amyl alcohol - n-amyl acetate - water at 303.15 K and atmospheric pressure
    Toikka, Maria
    Vernadskaya, Victoria
    Samarov, Artemiy
    FLUID PHASE EQUILIBRIA, 2018, 471 : 68 - 73
  • [28] KETOXIME ESTERS WITH AN N-AMYL RESPECTIVELY OPTICALLY-ACTIVE AMYL GROUP
    MOHR, K
    ZASCHKE, H
    WEISSFLOG, W
    ZEITSCHRIFT FUR CHEMIE, 1987, 27 (12): : 445 - 445
  • [29] Phytochemical reductions. IV. a) The formation from n-Amyl alcohol through yeast. b) Observations on the natural occurences of n-amyl-alcohol
    Neuberg, C
    Nord, FF
    BIOCHEMISCHE ZEITSCHRIFT, 1914, 62 : 482 - 488
  • [30] Kinetics and Mechanism of the Oxidative Conversion of n-Amyl Alcohol to Valeric Acid on a Modified Zeolite Catalyst
    A. M. Aliev
    M. F. Bakhmanov
    F. A. Agaev
    V. Sh. Agaev
    Z. A. Shabanova
    A. R. Safarov
    Russian Journal of Physical Chemistry A, 2018, 92 : 656 - 662