Extraction of boron with diols in petroleum benzine and n-amyl alcohol

被引:0
|
作者
Ozay, P [1 ]
Yurdakoc, M [1 ]
Karakaplan, M [1 ]
Hosgören, H [1 ]
机构
[1] Dokuz Eylul Univ, Dept Chem, Fac Arts & Sci, TR-35160 Buca Izmir, Turkey
关键词
boron; diols; extraction; benzine; n-amyl alcohol;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present work, the solvent extraction of boron with 2-ethyl-1,3-hexanediol (EHD), 1,2-dihydroxy-4-oxadodecane (DHD) and 3-(4-tert-butylphenoxy)-1,2-propanediol (BFPD) in petroleum benzine and n-amyl alcohol was thoroughly studied as a function of equilibrium pH. The pH(0.5) values for EHD, DHD and BFPD were determined from R %-pH graphs as 8.3, 2.7 and 2.3 in n-amyl alcohol, respectively. The extraction efficiencies of these diols were also comparatively investigated. The extraction efficiency in both solvents for each extractant was ranged from 78 to 98%. Stripping of boron was achieved as 96% for EHD with NaOH and 81% for BFPD with H2SO4.
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页码:1277 / 1284
页数:8
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