A convenient synthesis of (E)-β-hydroxyvinyltrimethylsilanes via 3,3-bis(trimethylsilyl)propene

被引：8
|
作者：
Princet, B [1 ]
Anselme, G [1 ]
Pornet, J [1 ]
机构：
[1] Univ Poitiers, Organ Synth Lab, F-86022 Poitiers, France
来源：
SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 19期
关键词：
D O I：
10.1080/00397919908085961
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
3,3-Bis(trimethylsilyl) propene, easily obtained by semi-hydrogenation from the recently reported (trimethylsilyl)prop-2-yne, reacts cleanly with aldehydes in the presence of titanium tetrachloride providing a new way to (E)-beta-hydroxyvinyltrimethylsilanes
引用
收藏
页码：3329 / 3340
页数：12
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