Preparation, crystal structures and properties of zinc complexes containing Bis(oxazoline) ligand

被引：0

作者：

Sun, Ying ^{[1
,2
]}

Jia, Wei-Guo ^{[2
]}

Li, Dan-Dan ^{[2
]}

Hao, Xiu-Yun ^{[2
]}

Zhou, Ying-Hua ^{[2
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China

[2] Anhui Normal Univ, Anhui Lab Mol Based Mat, Key Lab Funct Mol Solids,Minist Educ, Ctr Nano Sci & Technol,Coll Chem & Mat Sci, Wuhu 241000, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2015年 / 1102卷

关键词：

Zinc; Bisoxaioline; Hydrolysis; Structure; CARBOXYESTER HYDROLYSIS; ASYMMETRIC CATALYSIS; PEPTIDE DEFORMYLASE; HYDROXIDE COMPLEX; MODEL; 1,4,7,10-TETRAAZACYCLODODECANE; INTERMEDIATE; REACTIVITY;

D O I：

10.1016/j.molstruc.2015.08.073

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three zinc complexes ([(DMOX)ZnX2], X = Cl (1), Br (2) or I (3)), where DMOX is 4,5-dihydro-2-(4,5-dihydro-4,4-dimethyloxazol-2-y1)-4,4-dimethyloxazole), have been fully characterized by single crystal X-ray diffraction, UV-vis, NMR and IR spectroscopy. Moreover, all zinc complexes showed activities in catalyzing hydrolysis of 4-nitrophenyl acetate (4-NA). And active species have been determined by pH titrations of [(DMOX)ZnI2] in catalyzing hydrolysis of 4-NA. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：210 / 215

页数：6

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