Syntheses, Crystal Structures and Electrochemical Properties of Cobalt and Nickel Complexes Containing Imidazole Ligand

被引：0

作者：

Wang Qing-Hua ^{[1
,2
]}

Yu Li-Li ^{[1
,2
]}

Liu Qi ^{[1
,2
,3
]}

Cheng Mei-Ling ^{[1
,2
]}

机构：

[1] Changzhou Univ, Sch Chem & Chem Engn, Changzhou 213164, Jiangsu, Peoples R China

[2] Changzhou Univ, Jiangsu Prov Key Lab Fine Petrochem Technol, Changzhou 213164, Jiangsu, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 27卷 / 05期

关键词：

cobalt complexes; nickel complex; imidazole; 2,3,5,6-tetrafluoroterephthalate; crystal structure; electrochemical property; METAL; FRAMEWORKS; SORPTION; DESIGN;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel complexes [M(ImH)(6)](tfbdc) (M=Co, Ni; ImH=imidazole, tfbdc=2,3,5,6-tetrafluoroterephthalate) were synthesized and characterized by elemental analysis, IR spectra, thermogravimetric analysis, cyclic voltammetry, and X-ray single crystal structure analysis. Both [Co(ImH)(6)](tfbdc) (1) and [Ni(ImH)(6)] (tfbdc) (2) all crystallize in the monoclinic system, space group P2(1)/c, and with Z=2. Metal ions have all octahedral geometry coordinated by six N atoms from six imidazole molecules. The independent components, [M(ImH)(6)](2+) cations and tfbdc anions are connected into a three-dimensional supramolecular network by N-H center dot center dot center dot O and C-H center dot center dot center dot F hydrogen bonds. CCDC: 739086, 1; 739088, 2.

引用

页码：989 / 995

页数：7

共 20 条

[1] Cañadas R, 2000, POLYHEDRON, V19, P2059
[2] Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework
Chen, Banglin
Yang, Yu
Zapata, Fatima
Qian, Guodong
Luo, Yongshi
Zhang, Jiahua
Lobkovsky, Emil B.
[J]. INORGANIC CHEMISTRY, 2006, 45 (22) : 8882 - 8886
[3] Pillared-layer microporous metal-organic frameworks constructed by robust hydrogen bonds.: Synthesis, characterization, and magnetic and adsorption properties of 2,2′-biimidazole and carboxylate complexes
Ding, BB
Weng, YQ
Mao, ZW
Lam, CK
Chen, XM
Ye, BH
[J]. INORGANIC CHEMISTRY, 2005, 44 (24) : 8836 - 8845
[4] EDDAOUDI M, 2002, SCIENCE, V0295
[5] Crystallized frameworks with giant pores:: Are there limits to the possible?
Férey, G
Mellot-Draznieks, C
Serre, C
Millange, F
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 217 - 225
[6] HELENA GM, 2005, J ORGANOMET CHEM, V690, P4063
[7] Rational design and crystal structure determination of a 3-D metal-organic jungle-gym-like open framework
Kitaura, R
Iwahori, F
Matsuda, R
Kitagawa, S
Kubota, Y
Takata, M
Kobayashi, TC
[J]. INORGANIC CHEMISTRY, 2004, 43 (21) : 6522 - 6524
[8] Li RX, 2010, CHINESE J INORG CHEM, V26, P609
[9] Liu YJ, 2008, CHINESE J INORG CHEM, V24, P610
[10] Nanoporous magnets of chiral and racemic [{Mn(HL)}2Mn{Mo(CN)7}2] with switchable ordering temperatures (TC=85 K ⇆ 106 K) driven by H2O sorption (L = N,N-dimethylalaninol)
Milon, Julie
Daniel, Marie-Christine
Kaiba, Abdellah
Guionneau, Philippe
Brandes, Stephane
Sutter, Jean-Pascal
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) : 13872 - 13878

← 1 2 →