The molecular structure of the phosphate mineral senegalite Al2(PO4)(OH)3•3H2O - A vibrational spectroscopic study

We have studied the mineral senagalite, a hydrated hydroxy phosphate of aluminium with formula Al-2(-PO4)(OH)(3)center dot 3H(2)O using a combination of electron microscopy and vibrational spectroscopy. Senegalite crystal aggregates shows tabular to prismatic habitus and orthorhombic form. The Raman spectrum is dominated by an intense band at 1029 cm(-1) assigned to the PO43- v(1) symmetric stretching mode. Intense Raman bands are found at 1071 and 1154 cm(-1) with bands of lesser intensity at 1110, 1179 and 1206 cm(-1) and are attributed to the PO43- v(3) antisymmetric stretching vibrations. The infrared spectrum shows complexity with a series overlapping bands. A comparison is made with spectra of other aluminium containing phosphate minerals such as augelite and turquoise. Multiple bands are observed for the phosphate bending modes giving support for the reduction of symmetry of the phosphate anion. Vibrational spectroscopy offers a means for the assessment of the structure of senagalite. (c) 2013 Elsevier B.V. All rights reserved.