Scheelite-Related Triple Molybdates KCaLn(MoO4)3 in K2MoO4-CaMoO4-Ln2(MoO4)3 (Ln = Nd, Sm, Eu, Gd) Systems: Synthesis and Characterization

被引：2
|
作者：
Kozhevnikova, N. M. [1 ]
机构：
[1] Russian Acad Sci, Baikal Inst Nat Management, Siberian Branch, Ulan Ude 670047, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 02期
关键词：
D O I：
10.1134/S0036023618020146
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Subsolidus phase ratios in K2MoO4-CaMoO4-Ln(2)(MoO4)(3) systems where Ln = Nd, Sm, Eu, and Gd, have been studied by vibrational spectroscopy, X-ray powder diffraction, and differential thermal analysis. Triple molybdates KCaLn(MoO4)(3) (Ln = Nd, Sm, Eu, and Gd) have been synthesized; they have a scheelite-derivative structure, monoclinic crystal system (space group P21/n). Their unit cell parameters have been determined, and IR and Raman spectra characterized.
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页码：157 / 161
页数：5
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