Scheelite-Related Triple Molybdates KCaLn(MoO4)3 in K2MoO4-CaMoO4-Ln2(MoO4)3 (Ln = Nd, Sm, Eu, Gd) Systems: Synthesis and Characterization

被引：2
|
作者：
Kozhevnikova, N. M. [1 ]
机构：
[1] Russian Acad Sci, Baikal Inst Nat Management, Siberian Branch, Ulan Ude 670047, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 02期
关键词：
D O I：
10.1134/S0036023618020146
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Subsolidus phase ratios in K2MoO4-CaMoO4-Ln(2)(MoO4)(3) systems where Ln = Nd, Sm, Eu, and Gd, have been studied by vibrational spectroscopy, X-ray powder diffraction, and differential thermal analysis. Triple molybdates KCaLn(MoO4)(3) (Ln = Nd, Sm, Eu, and Gd) have been synthesized; they have a scheelite-derivative structure, monoclinic crystal system (space group P21/n). Their unit cell parameters have been determined, and IR and Raman spectra characterized.
引用
收藏
页码：157 / 161
页数：5
相关论文
共 50 条
  • [1] Scheelite-Related Triple Molybdates KCaLn(MoO4)3 in K2MoO4–CaMoO4–Ln2(MoO4)3 (Ln = Nd, Sm, Eu, Gd) Systems: Synthesis and Characterization
    N. M. Kozhevnikova
    Russian Journal of Inorganic Chemistry, 2018, 63 : 157 - 161
  • [2] Synthesis and study of ternary molybdates RbCaR(MoO4)3 with a scheelite-like structure in Rb2MoO4-CaMoO4-R2(MoO4)3 systems (R = Nd, Sm, Eu, Gd)
    Kozhevnikova, N. M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (12) : 1518 - 1521
  • [3] Phase formation in the systems Li2MoO4-K2MoO4-Ln2(MoO4)3 (Ln = La, Nd, Dy, Er) and properties of triple molybdates LiKLn2(MoO4)4
    Basovich, OM
    Khaikina, EG
    Solodovnikov, SF
    Tsyrenova, GD
    JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (05) : 1580 - 1588
  • [4] Synthesis and study of ternary molybdates RbCaR(MoO4)3 with a scheelite-like structure in Rb2MoO4–CaMoO4–R2(MoO4)3 systems (R = Nd, Sm, Eu, Gd)
    N. M. Kozhevnikova
    Russian Journal of Inorganic Chemistry, 2016, 61 : 1518 - 1521
  • [5] Phase relations in the K2MoO4–Ln2(MoO4)3–Zr(MoO4)2 (Ln = La–Lu, Y) systems
    A. V. Logvinova
    B. G. Bazarov
    Yu. L. Tushinova
    J. G. Bazarova
    Inorganic Materials, 2017, 53 : 1286 - 1292
  • [6] Tl2MoO4-Pr2(MoO4)3 system and new molybdates Tl5Ln(MoO4)4
    Basovich, OM
    Khaikina, EG
    Solodovnikov, SF
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2000, 45 (10) : 1586 - 1590
  • [7] STUDY OF THE BAMOO4-LN2(MOO4)3 (LN=ND,SM,YB) SYSTEMS
    VAKULYUK, VV
    EVDOKIMOV, AA
    KHOMCHENKO, GP
    ZHURNAL NEORGANICHESKOI KHIMII, 1982, 27 (07): : 1802 - 1806
  • [8] Phase Relations in the K2MoO4-Ln2(MoO4)3-Zr(MoO4)2 (Ln = La-Lu, Y) Systems
    Logvinova, A. V.
    Bazarov, B. G.
    Tushinova, Yu. L.
    Bazarova, J. G.
    INORGANIC MATERIALS, 2017, 53 (12) : 1286 - 1292
  • [9] Heat capacity, entropy of Ln2(MoO4)3 (Ln = La, Sm, and Gd), and the high-temperature enthalpy of Ln2(MoO4)3 (Ln = Eu, Dy, and Ho)
    V. M. Lazarev
    Y. L. Suponitskiy
    S. E. Liashenko
    Russian Journal of Physical Chemistry A, 2016, 90 : 911 - 913
  • [10] Heat capacity, entropy of Ln2(MoO4)3 (Ln = La, Sm, and Gd), and the high-temperature enthalpy of Ln2(MoO4)3 (Ln = Eu, Dy, and Ho)
    Lazarev, V. M.
    Suponitskiy, Y. L.
    Liashenko, S. E.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 90 (05) : 911 - 913
12345