On the information capacity of the electronic spectra of humic substances

被引:0
|
作者
Kudeyarova, AY [1 ]
机构
[1] Russian Acad Sci, Inst Physicochem & Biol Problems Soil Sci, Pushchino 142292, Moscow Oblast, Russia
关键词
D O I
暂无
中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
A new approach to the recording and interpretation of the electronic spectra of humic substances, which can help evaluate their electron-donating properties by the intensity of electron transitions in the ultraviolet region of the spectrum, was proposed. It was found that the electron-donating properties of humus were affected by nitrogen and phosphorus compounds. With a modernized procedure of spectrum recording, it was found that the electron-donating properties of humus changed under the effect of nitrogen compounds mainly because of the increase in mobility of the pi -electron cloud of benzene rings. The effect of phosphates was primarily manifested with respect to the substituents in benzene rings, where free pi -electrons accumulated due to the increased number of C=C bonds.
引用
收藏
页码:1180 / 1187
页数:8
相关论文
共 50 条
  • [41] On the nature of humic substances
    G. N. Fedotov
    S. A. Shoba
    Eurasian Soil Science, 2015, 48 : 1292 - 1299
  • [42] HUMIC SUBSTANCES IN GROUNDWATER
    THURMAN, EM
    MALCOLM, RL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 89 - ENVR
  • [43] Radioiodination of humic substances
    Franke, K.
    Kupsch, H.
    RADIOCHIMICA ACTA, 2010, 98 (06) : 333 - 339
  • [44] Information capacity of electronic vision systems
    Taubkin, II
    Trishenkov, MA
    INFRARED PHYSICS & TECHNOLOGY, 1996, 37 (06) : 675 - 693
  • [45] POSSIBILITIES FOR SEPARATION OF HUMIC AND NON HUMIC SUBSTANCES
    DANNEBERG, OH
    BODENKULTUR, 1981, 32 (02): : 93 - 104
  • [46] Activation of persulfate by humic substances: Stoichiometry and changes in the optical properties of the humic substances
    Kim, Cheolyong
    Chin, Yu-Ping
    Son, Heejong
    Hwang, Inseong
    Water Research, 2022, 212
  • [47] Activation of persulfate by humic substances: Stoichiometry and changes in the optical properties of the humic substances
    Kim, Cheolyong
    Chin, Yu-Ping
    Son, Heejong
    Hwang, Inseong
    WATER RESEARCH, 2022, 212
  • [48] Evolving factor analysis of synchronous fluorescence spectra of humic substances in the presence of Cu(II)
    Esteves, da Silva, J. C. G.
    Machado, A. A. S. C.
    Capacity Management Review, 23 (03):
  • [49] FT-IR SPECTRA OF HUMIC SUBSTANCES EXTRACTED WITH DIPOLAR APROTIC-SOLVENTS
    PICCOLO, A
    RAUSA, R
    CALEMMA, V
    CHEMOSPHERE, 1989, 18 (9-10) : 1927 - 1933
  • [50] On the origin of the constituents underlying the absorption spectra of humic substances and chromophoric dissolved organic matter
    Del Vecchio, R
    Blough, NV
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U805 - U805