On the information capacity of the electronic spectra of humic substances

被引:0
|
作者
Kudeyarova, AY [1 ]
机构
[1] Russian Acad Sci, Inst Physicochem & Biol Problems Soil Sci, Pushchino 142292, Moscow Oblast, Russia
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中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
A new approach to the recording and interpretation of the electronic spectra of humic substances, which can help evaluate their electron-donating properties by the intensity of electron transitions in the ultraviolet region of the spectrum, was proposed. It was found that the electron-donating properties of humus were affected by nitrogen and phosphorus compounds. With a modernized procedure of spectrum recording, it was found that the electron-donating properties of humus changed under the effect of nitrogen compounds mainly because of the increase in mobility of the pi -electron cloud of benzene rings. The effect of phosphates was primarily manifested with respect to the substituents in benzene rings, where free pi -electrons accumulated due to the increased number of C=C bonds.
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页码:1180 / 1187
页数:8
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