Thermomechanical and tensile properties of gamma-ray irradiated blends of cis-polyisoprene and trans-polyisoprene

被引:6
|
作者
Baboo, Mahesh [1 ]
Sharma, Kananbala [1 ]
Saxena, N. S. [1 ]
Kumar, Manmohan [2 ]
机构
[1] Univ Rajasthan, Semicond & Polymer Sci Lab, Jaipur 302055, Rajasthan, India
[2] Bhabha Atom Res Ctr, RPCD, Bombay 400085, Maharashtra, India
来源
POLYMER ENGINEERING AND SCIENCE | 2013年 / 53卷 / 02期
关键词
NATURAL-RUBBER; MECHANICAL-PROPERTIES; ELECTRON-BEAM; RADIATION; IMPROVEMENT;
D O I
10.1002/pen.23271
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In the present article, the effect of ?-ray irradiation of doses 14.85, 30, and 45 kGy on the thermomechanical and tensile properties of blends of cis-polyisoprene and trans-polyisoprene have been investigated. The results on thermomechanical properties show that glass transition temperature increases and height of tan d of material decreases with increasing radiation dose. Tensile measurements reveal that all the tensile properties like tensile strength, Young's modulus, and toughness also show an increasing trend with increasing dose of radiation. This increasing behavior of both thermomechanical and tensile properties has been explained through crystallinity and crosslink density induced by radiation. POLYM. ENG. SCI. 2013. (c) 2012 Society of Plastics Engineers
引用
收藏
页码:443 / 451
页数:9
相关论文
共 50 条
  • [21] SOLUTION PROPERTIES OF POLYBUTADIENE AND TRANS-POLYISOPRENE FRACTIONS
    COOPER, W
    VAUGHAN, G
    EAVES, DE
    JOURNAL OF POLYMER SCIENCE, 1962, 59 (168): : 241 - &
  • [22] Mechanical Properties and Rheological Behavior of Dynamically Vulcanized Trans-Polyisoprene/Polypropylene Blends
    Sun, Hongguang
    He, Peng
    Zhao, Shugao
    Chen, Zhanxun
    JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2011, 50 (07): : 1423 - 1429
  • [23] PROPERTIES OF CIS-POLYISOPRENE MODIFIED BY POLYSTYRENE IN THE LATEX STAGE
    ERMILOVA, NV
    KUZNETSOV, VL
    REMIZOVA, AA
    TARASOVA, ZN
    FEDYUKIN, LD
    COLLOID JOURNAL OF THE USSR, 1978, 40 (03): : 452 - 455
  • [24] Modulation of shape memory properties of trans-polyisoprene by sulfur
    Zhang, Tao
    Zhao, Wenli
    Cao, Zerong
    Liang, Yurong
    PHYSICA SCRIPTA, 2024, 99 (12)
  • [25] Strain-induced crystallization in cis- and trans-polyisoprene blends: Effect of molecular weight of trans-PI
    Manzur, A
    Rubio, L
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1997, B36 (01): : 103 - 115
  • [26] Vulcanizates of epoxidized trans-polyisoprene: morphology, mechanical and dynamic properties
    Wei Yao
    Huafeng Shao
    Jing Sun
    Aihua He
    Mingzhe Han
    Baoshen Huang
    Polymer Bulletin, 2014, 71 : 3151 - 3162
  • [27] Effect of Temperature on Thermal Transport and Mechanical Properties of Trans-polyisoprene
    Baboo, Mahesh
    Dixit, Manasvi
    Sharma, Kananbala
    Saxena, N. S.
    5TH INTERNATIONAL CONFERENCE ON THERMOPHYSICAL PROPERTIES, 2010, 1249 : 87 - 90
  • [28] Vulcanizates of epoxidized trans-polyisoprene: morphology, mechanical and dynamic properties
    Yao, Wei
    Shao, Huafeng
    Sun, Jing
    He, Aihua
    Han, Mingzhe
    Huang, Baoshen
    POLYMER BULLETIN, 2014, 71 (12) : 3151 - 3162
  • [29] Stress-induced crystallization properties of natural and synthetic cis-polyisoprene
    Trabelsi, S
    Albouy, PA
    Rault, J
    RUBBER CHEMISTRY AND TECHNOLOGY, 2004, 77 (02): : 303 - 316
  • [30] STUDY OF RHEOLOGICAL PROPERTIES OF POLYDISPERSE CIS-POLYISOPRENE IN PRESENCE OF OLIGOESTER ACRYLATES
    MEZHIKOVSKII, SM
    BERLIN, AA
    VASILCHENKO, EI
    PROZOROVSKAYA, NV
    FRENKEL, RS
    TUGOV, II
    KUZMINA, EA
    EVSTRATOV, VF
    CHURAKOVA, IK
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1977, 19 (12): : 2719 - 2725