Diphenylphosphanylsulfoximines as ligands in iridium-catalyzed asymmetric imine hydrogenations

被引：171
|
作者：
Moessner, C [1 ]
Bolm, C [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 46期
关键词：
amines; asymmetric catalysis; hydrogenation; imines; sulfoximines;
D O I：
10.1002/anie.200502482
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Easily accessible phosphine-substituted sulfoximines 2 have been applied in Ir-catalyzed asymmetric hydrogenations of acylic N-arylated imines 1. The amines 3 are formed under mild conditions in high yields with excellent ee values. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7564 / 7567
页数：4
相关论文
共 50 条
  • [31] Iridium-catalyzed asymmetric hydrogenation of olefins using TIQ phosphine-oxazoline ligands
    Chakka, Sai Kumar
    Peters, Byron K.
    Andersson, Pher G.
    Maguire, Glenn E. M.
    Kruger, Hendrik G.
    Govender, Thavendran
    TETRAHEDRON-ASYMMETRY, 2010, 21 (18) : 2295 - 2301
  • [32] Iridium-Catalyzed Asymmetric Allylic Amination Reactions with N-Aryl Phosphoramidite Ligands
    Zhang, Xiao
    Liu, Wen-Bo
    Cheng, Qiang
    You, Shu-Li
    ORGANOMETALLICS, 2016, 35 (15) : 2467 - 2472
  • [33] A family of novel chiral N, P ligands in iridium-catalyzed asymmetric hydrogenation.
    Zhang, XM
    Tang, WJ
    Wang, WM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U199 - U199
  • [34] Iridium-Catalyzed Asymmetric Hydrogenation of Dialkyl Imines
    Wang, Zheng
    Yang, Xin-Yi
    Xu, Yue
    Zhou, Qi-Lin
    CCS CHEMISTRY, 2024, 6 (04): : 905 - 911
  • [35] Iridium-Catalyzed Asymmetric Allylic Aromatization Reaction
    Liu, Xi-Jia
    Zheng, Chao
    Yang, Yi-Han
    Jin, Shicheng
    You, Shu-Li
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (31) : 10493 - 10499
  • [36] Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Enamines
    Baeza, Alejandro
    Pfaltz, Andreas
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (10) : 2266 - 2269
  • [37] Iridium-catalyzed asymmetric hydroalkynylation reactions of oxabenzonorbornadienes
    Hu, Jun
    Yang, Qingjing
    Xu, Jianbin
    Huang, Chao
    Fan, Baomin
    Wang, Jun
    Lin, Chengyuan
    Bian, Zhaoxiang
    Chan, Albert S. C.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (05) : 814 - 820
  • [38] Iridium-Catalyzed Asymmetric Hydrogenation of Cyclic Enamines
    Hou, Guo-Hua
    Xie, Jian-Hua
    Yan, Pu-Cha
    Zhou, Qi-Lin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (04) : 1366 - +
  • [39] Revisiting the Stereodetermining Step in Enantioselective Iridium-Catalyzed Imine Hydrogenation
    Tutkowski, Brandon
    Kerdphon, Sutthichat
    Lime, Elaine
    Helquist, Paul
    Andersson, Pher G.
    Wiest, Olaf
    Norrby, Per-Ola
    ACS CATALYSIS, 2018, 8 (01): : 615 - 623
  • [40] Iridium-Catalyzed Asymmetric Synthesis of Functionally Rich Molecules Enabled by (Phosphoramidite,Olefin) Ligands
    Rossler, Simon L.
    Petrone, David A.
    Carreira, Erick M.
    ACCOUNTS OF CHEMICAL RESEARCH, 2019, 52 (09) : 2657 - 2672
12345