Diphenylphosphanylsulfoximines as ligands in iridium-catalyzed asymmetric imine hydrogenations

被引：171
|
作者：
Moessner, C [1 ]
Bolm, C [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 46期
关键词：
amines; asymmetric catalysis; hydrogenation; imines; sulfoximines;
D O I：
10.1002/anie.200502482
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Easily accessible phosphine-substituted sulfoximines 2 have been applied in Ir-catalyzed asymmetric hydrogenations of acylic N-arylated imines 1. The amines 3 are formed under mild conditions in high yields with excellent ee values. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7564 / 7567
页数：4
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