First total synthesis of an analogue of (±)-hypargenin B

被引:0
|
作者
Li, AP [1 ]
Wang, H [1 ]
Zhang, CL [1 ]
Wu, TX [1 ]
Pan, XF [1 ]
机构
[1] Lanzhou Univ, Natl Lab Appl Organ Chem, Dept Chem, Lanzhou 730000, Peoples R China
关键词
hypargenin B; diterpene; intramolecular; steroselective;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
First total synthesis of (+/-)-hypargenin B methyl ether 2 was accomplished via a strategy of AC-->ABC, in which CrO(3)/H(2)O/NaOAc/HOAc system was utilized for introducing 7-keto group in order to avoid dehydration of benzyl tertiary alcohol.
引用
收藏
页码:133 / 134
页数:2
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