First total synthesis of an analogue of (±)-hypargenin B

被引：0

作者：

Li, AP ^{[1
]}

Wang, H ^{[1
]}

Zhang, CL ^{[1
]}

Wu, TX ^{[1
]}

Pan, XF ^{[1
]}

机构：

[1] Lanzhou Univ, Natl Lab Appl Organ Chem, Dept Chem, Lanzhou 730000, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2002年 / 13卷 / 02期

关键词：

hypargenin B; diterpene; intramolecular; steroselective;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

First total synthesis of (+/-)-hypargenin B methyl ether 2 was accomplished via a strategy of AC-->ABC, in which CrO(3)/H(2)O/NaOAc/HOAc system was utilized for introducing 7-keto group in order to avoid dehydration of benzyl tertiary alcohol.

引用

页码：133 / 134

页数：2

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