Morphology, Structure, and Crystallization of LaCl Modified Hollow Glass Microspheres/Poly(vinylidenefluoride) Composites

Poly(vinylidene fluoride)/hollow glass microspheres (PVDF/HGMs) composites were prepared by using lanthanum chloride surface modified HGMs. The morphology, structure, and crystallization of the PVDF/HGMs composites were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), and differential scanning calorimetry (DSC), respectively. The results showed that the interaction between the HGMs and the PVDF was improved by lanthanum chloride modification. The crystal structure of the PVDF was not changed by the HGMs, but the crystallinity was decreased. In addition, the Jeziorny and the Mo methods were used to analyze the non-isothermal crystallization kinetics. The results showed that the HGMs decreased the crystallization rates and extended the crystallization time of the PVDF.