Effects of the ether oxygen atom in alkyl side chains on the physical properties of piperidinium ionic liquids

被引：15
|
作者：
Nokami, T. [1 ,2 ]
Yamashita, T. [1 ]
Komura, T. [1 ]
Handa, N. [1 ]
Shimizu, M. [1 ]
Yamaguchi, K. [1 ]
Domi, Y. [1 ,2 ]
Usui, H. [1 ,2 ]
Sakaguchi, H. [1 ,2 ]
Itoh, T. [1 ,2 ]
机构：
[1] Tottori Univ, Grad Sch Engn, Dept Chem Biotechnol, 4-101 Koyama Minami, Tottori 6808552, Japan
[2] Tottori Univ, Grad Sch Engn, Ctr Res Green Sustainable Chem, 4-101 Koyama Minami, Tottori 6808552, Japan
来源：
FARADAY DISCUSSIONS | 2018年 / 206卷
关键词：
LIPASE CATALYZED REACTION; LITHIUM BATTERY; PHYSICOCHEMICAL PROPERTIES; FUNCTIONAL-GROUPS; SOLVENT SYSTEM; ELECTROLYTES; DESIGN; CATIONS; ANION;
D O I：
10.1039/c7fd00142h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Various types of piperidinium ionic liquids (ILs) equipped with an oxygen atom-containing alkyl side chain on the positively charged nitrogen atom were systematically synthesized and their physical properties investigated. The thermal stability, viscosity, electrochemical window, and ion conductivity were influenced significantly by changing the position of the oxygen atom in the alkyl chain. Although the lowest viscosity was recorded for 1-((2-methoxyethoxy)methyl)-1-methylpiperidin-1-ium bis(trifluoromethylsulfonyl)amide ([PP1MEM][Tf2N]), 1-methyl-1-(2-propoxyethyl)piperidin-1-ium bis(trifluoromethylsulfonyl) amide ([PP1PE][Tf2N]) can be recommended as the best IL as an electrolyte due to its low viscosity and high thermal and electrochemical stability among the seven ILs tested.
引用
收藏
页码：523 / 534
页数：12
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