The Effect of Chloride on Passive Oxide Film Breakdown on Stainless Steels and Aluminum

被引：8

作者：

Natishan, P. M. ^{[1
]}

O'Grady, W. E. ^{[1
]}

Martin, F. J. ^{[1
]}

Rayne, R. J. ^{[2
]}

Kahn, H. ^{[3
]}

Heuer, A. H. ^{[3
]}

机构：

[1] Naval Res Lab, Div Chem, Washington, DC 20375 USA

[2] Naval Res Lab, Mat Sci & Tech Div, Washington, DC USA

[3] Case Western Reserve Univ, Dept Mat Sci & Engn, Cleveland, OH 44105 USA

来源：

CRITICAL FACTORS IN LOCALIZED CORROSION 7 | 2012年 / 41卷 / 25期

关键词：

X-RAY PHOTOELECTRON; PITTING CORROSION; AES ANALYSIS; XPS; ION; SPECTROSCOPY; METALS; MODEL; LAYER; CR;

D O I：

10.1149/1.3697577

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The evidence for adsorption or incorporation of chloride ions (Cl-) in the passive oxide film on stainless steels and Fe-Cr alloys appears to be contradictory, with some investigators reporting Cl- in the oxide and others reporting its absence. We consider this issue by determining Cl- adsorption and/or incorporation as a function of potential (below the pitting potential) on 316L stainless steel using Xray photoelectron spectroscopy and compare our results to the literature on uptake of Cl- by stainless steels and to studies on uptake of Cl- on aluminum. The important finding is that no Cl- is observed in the oxide film on 316L stainless steel whereas in the case of aluminum, Cl- is incorporated into the oxide film. We present the case for those instances where Cl- is observed in the oxide films on stainless steels and Fe-Cr alloys, these observations are a result of the experimental procedures employed.

引用

页码：49 / 57

页数：9

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