Synthesis, structure, and luminescence properties of arylpyridine-substituted terpyridine Zn(II) and Cd(II) complexes

被引：14
|
作者：
Kubota, Emi [1 ]
Lee, Young Hoon [1 ]
Fuyuhiro, Akira [2 ]
Kawata, Satoshi [3 ]
Harrowfield, Jack M. [4 ]
Kim, Yang [5 ]
Hayami, Shinya [1 ,6 ]
机构：
[1] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Kumamoto 8608555, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
[3] Fukuoka Univ, Fac Sci, Dept Chem, Jonan Ku, Fukuoka 8140180, Japan
[4] Univ Strasbourg, Inst Sci & Ingn Supramol, Lab Chim Supramol, F-67083 Strasbourg, France
[5] Kosin Univ, Dept Chem & Adv Mat, Pusan 606701, South Korea
[6] JST, CREST, Chiyoda Ku, Tokyo 1020075, Japan
来源：
POLYHEDRON | 2013年 / 52卷
关键词：
Crystal structure; Luminescence; Metal complex; Heteroarylterpyridine; PI-STACKING INTERACTIONS; 1D COORDINATION NETWORKS; SUPRAMOLECULAR STRUCTURE; MOLECULAR TECTONICS; LIGAND; POLYPYRIDYL; FLUORESCENT; ALKYLATION; DRIVEN;
D O I：
10.1016/j.poly.2012.08.054
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two terpyridine derivatives, 4'-(4-(pyridin-4-yl)phenyl)-[2,2':6',2 '']terpyridine (L1) and 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2 '']terpyridine (L2) have been synthesized by palladium-catalyzed cross-coupling reactions, and their metal complexes [Zn(L1)(2)](ClO4)(2)center dot 2MeOH center dot CHCl3 (1) and [Cd(L2)(2)] (ClO4)(2)center dot DMF.2.8H(2)O (2) characterized by single crystal X-ray crystallography and spectroscopic methods including electronic absorption and emission measurements. In the crystalline materials, both metal ions have the expected pseudo-octahedral N-6 coordination environment and the lattice structures appear to be influenced by aromatic aromatic interactions involving the heteroaryl tails and the pyridyl rings of the terpyridine units. In solution and in the solid state, the complexes display blue emission attributed to an intramolecular charge transfer transition. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：435 / 441
页数：7
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