Coarse grained open system quantum dynamics

被引:6
|
作者
Thanopulos, Ioannis [1 ]
Brumer, Paul [2 ,3 ]
Shapiro, Moshe [1 ,4 ]
机构
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z3, Canada
[2] Univ Toronto, Chem Phys Theory Grp, Dept Chem, Toronto, ON M5S 3H6, Canada
[3] Univ Toronto, Ctr Quantum Informat & Quantum Control, Toronto, ON M5S 3H6, Canada
[4] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel
来源
JOURNAL OF CHEMICAL PHYSICS | 2008年 / 129卷 / 19期
关键词
differential equations; matrix algebra; quantum theory; Schrodinger equation;
D O I
10.1063/1.3010370
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that the quantum dynamics of a system comprised of a subspace Q coupled to a larger subspace P can be recast as a reduced set of "coarse grained" ordinary differential equations with constant coefficients. These equations can be solved by a single diagonalization of a general complex matrix. The method makes no assumptions about the strength of the couplings between the Q and the P subspaces, nor is there any limitation on the initial population in P. The utility of the method is demonstrated via computations in three following areas: molecular compounds, photonic materials, and condensed phases.
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页数:5
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