Ditopic bis(N,N′,N′-substituted 1,2-ethanediamine) ligands: synthesis and coordination chemistry

被引：4
|
作者：
Roesch, Andreas [1 ]
Herzog, Christoph M. [1 ]
Schreiner, Simon H. F. [1 ]
Goerls, Helmar [2 ]
Kretschmer, Robert [2 ,3 ]
机构：
[1] Univ Regensburg, Inst Inorgan Chem, Univ Str 31, D-93053 Regensburg, Germany
[2] Friedrich Schiller Univ Jena, Inst Inorgan & Analyt Chem IAAC, Humboldtstr 8, D-07743 Jena, Germany
[3] Friedrich Schiller Univ Jena, Jena Ctr Soft Matter JCSM, Philosophenweg 7, D-07743 Jena, Germany
来源：
DALTON TRANSACTIONS | 2020年 / 49卷 / 39期
关键词：
BRIDGED BIS(GUANIDINATE) LIGAND; ANSA BIS(AMIDINATE) LIGAND; MAIN-GROUP ELEMENTS; STRUCTURAL-CHARACTERIZATION; LINKED BIS(AMIDINATE); HETEROMETALLIC COMPLEXES; LACTIDE POLYMERIZATION; BINUCLEATING LIGANDS; CATALYTIC-ACTIVITY; CRYSTAL-STRUCTURES;
D O I：
10.1039/d0dt03124k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of two different types of bis(N,N',N'-substituted 1,2-ethanediamine)s, bridged either through the secondary (type 1) or tertiary (type 2) amine groups is reported. Selected protio-ligands have been applied in subsequent metallation reactions using aluminium, magnesium, tin, and zinc sources allowing to isolate five mononuclear and eight dinuclear complexes. All complexes have been fully characterized and their solid-state structures have been studied by means of single-crystal X-ray diffraction analysis. Nine of the 13 complexes carry reactive alkyl, amide or hydride groups, which indicates their potential as catalysts or supports for (transition) metals.
引用
收藏
页码：13818 / 13828
页数：11
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