Ca2(H3O)2[V10O28]•16H2O

被引：15
|
作者：
Strukan, N [1 ]
Cindric, M [1 ]
Kamenar, B [1 ]
机构：
[1] Univ Zagreb, Fac Sci, Lab Gen & Inorgan Chem, Zagreb 10000, Croatia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270198013468
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of dicalcium bis(oxonium) decavanadate hexadecahydrate has been determined by X-ray analysis, The main feature of the structure is the [V10O28](6-) anion, built up from ten distorted edge-sharing VO6 octahedra with well established structures. Each Ca2+ ion is surrounded by seven water molecules in the form of a distorted pentagonal bipyramid, Water H atoms, as well as those of the H3O+ ions, participate in a complicated three-dimensional hydrogen-bonding system.
引用
收藏
页码：291 / 293
页数：3
相关论文
共 50 条
  • [11] Synthesis and characterization of decavanadates:: X-ray crystal structures of (H3O)2[M(H2O)6]2[V10O28H6]•4H2O (M= Co, Ni) and Na[H3N(CH2)2NH3]2.5[V10O28]•5H2O
    Khan, MI
    Tabussum, S
    Zheng, C
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2000, 30 (09): : 1773 - 1790
  • [12] A novel polyoxometalate supramolecular compound:: [La(H2O)9]2[V10O28]•8H2O
    Peng, XH
    Li, YZ
    Cai, LX
    Wang, LF
    Wu, JG
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : I111 - I113
  • [13] Ba-3[V10O28]center dot 19H(2)O
    Kamenar, B
    Cindric, M
    Strukan, N
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 1338 - 1341
  • [14] THE REDEFINITION OF GUNTERITE, Na4Ca[V10O28]•20H2O
    Kampf, Anthony R.
    Cooper, Mark A.
    Hawthorne, Frank C.
    Hughes, John M.
    Nash, Barbara P.
    Adams, Paul M.
    CANADIAN MINERALOGIST, 2022, 60 (02): : 361 - 368
  • [15] Hexaaquachromium(III) trihydrogen isopolyvanadate [Cr(H2O)6]H3[V10O28] • 2H2O: Synthesis and study
    Stepnova, A. F.
    Holguin Quinones, S.
    Kaziev, G. Z.
    Kirichenko, O. A.
    Oreshkina, A. V.
    Morales Sanchez, L. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (06) : 475 - 477
  • [16] Mg2Na2V10O28•20H2O and Mg3V10O28•28H2O
    Iida, A
    Ozeki, T
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : I43 - I46
  • [17] Hexaaquachromium(III) trihydrogen isopolyvanadate [Cr(H2O)6]H3[V10O28] · 2H2O: Synthesis and study
    A. F. Stepnova
    S. Holguin Quiñones
    G. Z. Kaziev
    O. A. Kirichenko
    A. V. Oreshkina
    L. A. Morales Sanchez
    Russian Journal of Coordination Chemistry, 2013, 39 : 475 - 477
  • [18] (NH4)4Na2[V10O28]•10H2O
    Fratzky, D
    Schneider, M
    Rabe, S
    Meisel, M
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : 740 - 741
  • [19] X-ray structural characterization of [Eu(H2O)8]2[V10O28]·8H2O
    Bull Chem Soc Jpn, 8 (1775-1779):
  • [20] X-ray structural characterization of [Eu(H2O)8]2[V10O28]•8H2O
    Naruke, H
    Yamase, T
    Kaneko, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (08) : 1775 - 1779
12345