Ca2(H3O)2[V10O28]•16H2O

被引:15
|
作者
Strukan, N [1 ]
Cindric, M [1 ]
Kamenar, B [1 ]
机构
[1] Univ Zagreb, Fac Sci, Lab Gen & Inorgan Chem, Zagreb 10000, Croatia
关键词
D O I
10.1107/S0108270198013468
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of dicalcium bis(oxonium) decavanadate hexadecahydrate has been determined by X-ray analysis, The main feature of the structure is the [V10O28](6-) anion, built up from ten distorted edge-sharing VO6 octahedra with well established structures. Each Ca2+ ion is surrounded by seven water molecules in the form of a distorted pentagonal bipyramid, Water H atoms, as well as those of the H3O+ ions, participate in a complicated three-dimensional hydrogen-bonding system.
引用
收藏
页码:291 / 293
页数:3
相关论文
共 50 条
  • [1] Ca2(H3O)2[V10O28]·16H2O
    Acta Crystallogr Sect C Cryst Struct Commun, pt 3 (291-293):
  • [2] WERNERBAURITE, {[Ca(H2O)7]2(H2O)2(H3O)2}{V10O28}, AND SCHINDLERITE, {[Na2(H2O)10](H3O)4}{V10O28}, THE FIRST HYDRONIUM-BEARING DECAVANADATE MINERALS
    Kampf, Anthony R.
    Hughes, John M.
    Marty, Joe
    Nash, Barbara
    CANADIAN MINERALOGIST, 2013, 51 (02): : 297 - 312
  • [3] Ba3[V10O28].19H2O
    Kamenar, Boris
    Cindric, Marina
    Strukan, Neven
    1996, Munksgaard Int Publ. Ltd., Copenhagen K, Denmark (52)
  • [4] Refinement of the crystal structure of K2Zn2V10O28 •16H2O
    Yakubovich, OV
    Anan'eva, EN
    Dimitrova, OV
    Urusov, VS
    DOKLADY PHYSICS, 2002, 47 (05) : 346 - 352
  • [5] Refinement of the crystal structure of K2Zn2V10O28 ⋅ 16H2O
    O. V. Yakubovich
    E. N. Anan’eva
    O. V. Dimitrova
    V. S. Urusov
    Doklady Physics, 2002, 47 : 346 - 352
  • [6] PreparationandCrystalStructureofaRare-earthSaltBasedontheDecavanadate(V10O286-):[Y(H2O)8]2[V10O28]·9H2O
    王敬平
    韩秋霞
    牛景杨
    结构化学, 2006, (03) : 333 - 337
  • [7] Synthesis, structural characterization, Hirshfeld surface analysis and conduction pathways of Na2Li2(H3O)2 [V10O28]•18H2O compound
    Ksiksi, Regaya
    Aissa, Taissir
    Zid, Mohamed Faouzi
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1263
  • [8] Mg2Ru2Cl10O•16H2O
    Boufas, Sihem
    Merazig, Hocine
    Bendjeddou, Lamia
    Denes, Georges
    Beghidja, Adel
    Moliterni, Anna Grazia
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2007, 63 : I7 - I9
  • [9] Synthesis and Crystal Structure of Two Decavanadates Cluster Metal Complexes: [Co(H2O)6]2[H2V10O28]•6H2O and (NH4)2[Ca(H2O)7]2[V10O28]
    Liu, Haixing
    Wang, Jing
    Jian, Fangfang
    Xiao, Hailian
    JOURNAL OF CLUSTER SCIENCE, 2009, 20 (03) : 621 - 627
  • [10] Synthesis and Crystal Structure of Two Decavanadates Cluster Metal Complexes: [Co(H2O)6]2[H2V10O28]·6H2O and (NH4)2[Ca(H2O)7]2[V10O28]
    Haixing Liu
    Jing Wang
    Fangfang Jian
    Hailian Xiao
    Journal of Cluster Science, 2009, 20 : 621 - 627