An alternate derivation of the Herman-Kluk (coherent state) semiclassical initial value representation of the time evolution operator

被引:0
|
作者
Miller, WH [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Kenneth S Pitzer Ctr Theoret Chem, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
关键词
D O I
10.1080/00268970110069029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is shown that the Herman-Kluk (or coherent state) initial value representation (IVR) of the semiclassical propagator (time evolution operator) can be obtained by application of a modified Filinov filtering procedure to the standard Van Vleck (coordinate space) expression for the propagator. This further illustrates the effective equivalence, semiclassically, of these various IVRs.
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页码:397 / 400
页数:4
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