Stoichiometry and phase behavior of carbon tetrachloride solvates of C-60

被引：24
|
作者：
Nagano, Y
Tamura, T
机构：
[1] Microcalorimetry Research Center, Faculty of Science, Osaka University
来源：
CHEMICAL PHYSICS LETTERS | 1996年 / 252卷 / 5-6期
关键词：
D O I：
10.1016/0009-2614(96)00170-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two solvated crystals of C-60 were formed from CCl4 solutions. It was found that the cubic solvated crystal is composed of a C-60(CCl4)(13) formula unit while the hexagonal crystal has a C-60(CCl4)(2) unit. These solvates have phase behavior comparable with that of cyclohexane solvates of C-60, being closely related to binary sphere mixtures with a characteristic diameter ratio of 0.58. The present calorimetric study strongly suggests that the C-60(CCl4)(13) crystal has an AB(13)-type structure, in which icosahedron clusters of CCl4 like those in the cyclohexane analogue are formed.
引用
收藏
页码：362 / 366
页数：5
相关论文
共 50 条
  • [11] GAS-PHASE REACTIONS OF THE BUCKMINSTERFULLERENE CATIONS C-60(.+), C-60(2+), AND C-60(.3+) WITH WATER, ALCOHOLS, AND ETHERS
    JAVAHERY, G
    PETRIE, S
    WINCEL, H
    WANG, J
    BOHME, DK
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) : 6295 - 6301
  • [12] SOLUTION BEHAVIOR OF BUCKMINSTERFULLERENE (C-60) IN BENZENE
    YING, QC
    MARECEK, J
    CHU, B
    JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (04): : 2665 - 2672
  • [13] DISSOLUTION AND REDUCTION BEHAVIOR OF C-60 FILMS
    WANG, WJ
    CHIN, HS
    YU, LJ
    WANG, BC
    SYNTHETIC METALS, 1995, 70 (1-3) : 1465 - 1468
  • [14] SOLID C-60 - A NEW FORM OF CARBON
    KRATSCHMER, W
    LAMB, LD
    FOSTIROPOULOS, K
    HUFFMAN, DR
    NATURE, 1990, 347 (6291) : 354 - 358
  • [15] MAGNETIC-BEHAVIOR OF ICOSAHEDRAL C-60
    ELSER, V
    HADDON, RC
    PHYSICAL REVIEW A, 1987, 36 (10): : 4579 - 4584
  • [16] CRYSTALLIZATION AND PHASE-TRANSITIONS IN C-60
    BYSZEWSKI, P
    DIDUSZKO, R
    KOWALSKA, E
    FINKFINOWICKI, J
    WITOWSKI, A
    APPLIED PHYSICS LETTERS, 1992, 61 (25) : 2981 - 2983
  • [17] The rotation and the phase transition in solid C-60
    Xu, ZJ
    Yan, JM
    CHINESE JOURNAL OF CHEMISTRY, 1996, 14 (06) : 481 - 489
  • [18] Orientational phase transitions in C-60 solid
    Dharamvir, K
    Jindal, VK
    DISORDERED MATERIALS - CURRENT DEVELOPMENTS -, 1996, 223 : 373 - 376
  • [19] FACILE AND SELECTIVE METHOD FOR THE SOLUTION-PHASE GENERATION OF C-60(-) AND C-60(2-)
    SUBRAMANIAN, R
    BOULAS, P
    VIJAYASHREE, MN
    DSOUZA, F
    JONES, MT
    KADISH, KM
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (16) : 1847 - 1848
  • [20] SOLID-STATE STUDIES ON C-60 SOLVATES GROWN FROM N-HEPTANE
    CEOLIN, R
    AGAFONOV, V
    BACHET, B
    GONTHIERVASSAL, A
    SZWARC, H
    TOSCANI, S
    KELLER, G
    FABRE, C
    RASSAT, A
    CHEMICAL PHYSICS LETTERS, 1995, 244 (1-2) : 100 - 104
12345