Efficient and Regioselective Ring-opening of Epoxides with Carboxylic Acid Catalyzed by Graphite Oxide

被引：2

作者：

Mirza-Aghayan, Maryam ^{[1
]}

Tavana, Mahdieh Molaee ^{[1
]}

Niazi, Elaheh Golam Alipour ^{[1
]}

Boukherroub, Rabah ^{[2
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran CCERCI, POB 14335-186, Tehran, Iran

[2] Univ Valenciennes, ISEN, Cent Lille, CNRS,Univ Lille,UMR 8520,IEMN, F-59000 Lille, France

来源：

LETTERS IN ORGANIC CHEMISTRY | 2020年 / 17卷 / 07期

关键词：

Ring-opening; epoxides; carboxylic acids; metal-free conditions; graphite oxide; 1,2-diester; ACETIC-ACID; OXIDATIVE AROMATIZATION; KINETIC RESOLUTION; ALCOHOLS; MILD; EPICHLOROHYDRIN; ESTERIFICATION; AZIRIDINES; REAGENT; NITRATE;

D O I：

10.2174/1570178616666190401194252

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient, simple and regioselective ring-opening reaction of epoxides with various carboxylic acids under metal-free conditions is reported. The ring-opening of epoxides takes place in the presence of graphite oxide as an efficient and available catalyst to produce the corresponding 2-hydroxy monoester and 1,2-diester derivatives in good yields. Regioselective attack of the nucleophile, short reaction times, metal-free conditions and reusability of catalyst are among the advantages of the present protocol.

引用

页码：532 / 538

页数：7

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