Efficient and Regioselective Ring-opening of Epoxides with Carboxylic Acid Catalyzed by Graphite Oxide

被引：2
|
作者：
Mirza-Aghayan, Maryam [1 ]
Tavana, Mahdieh Molaee [1 ]
Niazi, Elaheh Golam Alipour [1 ]
Boukherroub, Rabah [2 ]
机构：
[1] Chem & Chem Engn Res Ctr Iran CCERCI, POB 14335-186, Tehran, Iran
[2] Univ Valenciennes, ISEN, Cent Lille, CNRS,Univ Lille,UMR 8520,IEMN, F-59000 Lille, France
来源：
LETTERS IN ORGANIC CHEMISTRY | 2020年 / 17卷 / 07期
关键词：
Ring-opening; epoxides; carboxylic acids; metal-free conditions; graphite oxide; 1,2-diester; ACETIC-ACID; OXIDATIVE AROMATIZATION; KINETIC RESOLUTION; ALCOHOLS; MILD; EPICHLOROHYDRIN; ESTERIFICATION; AZIRIDINES; REAGENT; NITRATE;
D O I：
10.2174/1570178616666190401194252
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient, simple and regioselective ring-opening reaction of epoxides with various carboxylic acids under metal-free conditions is reported. The ring-opening of epoxides takes place in the presence of graphite oxide as an efficient and available catalyst to produce the corresponding 2-hydroxy monoester and 1,2-diester derivatives in good yields. Regioselective attack of the nucleophile, short reaction times, metal-free conditions and reusability of catalyst are among the advantages of the present protocol.
引用
收藏
页码：532 / 538
页数：7
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