Ordered macro-microporous metal-organic framework single crystals

被引：995
|
作者：
Shen, Kui [1 ]
Zhang, Lei [1 ]
Chen, Xiaodong [1 ]
Liu, Lingmei [2 ]
Zhang, Daliang [3 ]
Han, Yu [2 ]
Chen, Junying [1 ]
Long, Jilan [1 ]
Luque, Rafael [4 ]
Li, Yingwei [1 ]
Chen, Banglin [5 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] KAUST, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
[3] KAUST, Imaging & Characterizat Core Lab, Thuwal 239556900, Saudi Arabia
[4] Univ Cordoba, Dept Quim Organ, Edificio Marie Curie,Carretera Nacl 4-A,Km 396, E-14014 Cordoba, Spain
[5] Univ Texas San Antonio, Dept Chem, One UTSA Circle, San Antonio, TX 78249 USA
来源：
SCIENCE | 2018年 / 359卷 / 6372期
基金：
中国国家自然科学基金;
关键词：
ZEOLITE; ARCHITECTURES; STABILITY; STRATEGY; GROWTH; ARRAYS; OXIDES;
D O I：
10.1126/science.aao3403
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
We constructed highly oriented and ordered macropores within metal-organic framework (MOF) single crystals, opening up the area of three-dimensional-ordered macro-microporous materials (that is, materials containing both macro-and micropores) in single-crystalline form. Our methodology relies on the strong shaping effects of a polystyrene nanosphere monolith template and a double-solvent-induced heterogeneous nucleation approach. This process synergistically enabled the in situ growth of MOFs within ordered voids, rendering a single crystal with oriented and ordered macro-microporous structure. The improved mass diffusion properties of such hierarchical frameworks, together with their robust single-crystalline nature, endow them with superior catalytic activity and recyclability for bulky-molecule reactions, as compared with conventional, polycrystalline hollow, and disordered macroporous ZIF-8.
引用
收藏
页码：206 / +
页数：5
相关论文
共 50 条
  • [41] Ordered Macro/Microporous Ionic Organic Framework for Efficient Separation of Toxic Pollutants from Water
    Fajal, Sahel
    Hassan, Atikur
    Mandal, Writakshi
    Shirolkar, Mandar M. M.
    Let, Sumanta
    Das, Neeladri
    Ghosh, Sujit K. K.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (01)
  • [42] Thermoelectric Properties of Highly Ordered Metal-Organic Framework Films
    Chen, Xin
    Wang, Zhengbang
    Lin, Pengtao
    Zhang, Kai
    Baumgart, Helmut
    Redel, Engelbert
    Woell, Christof
    EMERGING NANOMATERIALS AND DEVICES, 2016, 75 (13): : 119 - 126
  • [43] Intermarriage of Halide Perovskites and Metal-Organic Framework Crystals
    Hou, Jingwei
    Wang, Zhiliang
    Chen, Peng
    Chen, Vicki
    Cheetham, Anthony K.
    Wang, Lianzhou
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (44) : 19434 - 19449
  • [44] Synthesis, Structure, and Characterization of a Microporous Metal-Organic Framework with PtS Topology
    Zhang, Qing-Feng
    Luo, Jun-Hua
    Yuan, Ai-Hua
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (10): : 1804 - 1807
  • [45] Microporous metal-organic framework materials for carbon dioxide capture and separation
    Chen, Banglin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [46] A two dimensional microporous metal-organic framework for selective gas separation
    Alawisi, Hussah
    Li, Bin
    Alfooty, Khalid
    Wu, Ling
    Xiang, Shengchang
    Wang, Hailong
    Chen, Banglin
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 50 : 106 - 109
  • [47] A novel polyoxometalate templated microporous metal-organic framework with electrochemical properties
    Wang, Xiuli
    Chang, Zhihan
    Lin, Hongyan
    Xu, Chuang
    Luan, Jian
    Liu, Guocheng
    Tian, Aixiang
    RSC ADVANCES, 2015, 5 (45) : 35535 - 35540
  • [48] A microporous metal-organic framework for gas-chromatographic separation of alkanes
    Chen, BL
    Liang, CD
    Yang, J
    Contreras, DS
    Clancy, YL
    Lobkovsky, EB
    Yaghi, OM
    Dai, S
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) : 1390 - 1393
  • [49] A microporous luminescent europium metal-organic framework for nitro explosive sensing
    Zhou, Xinhui
    Li, Honghui
    Xiao, Hongping
    Li, Liang
    Zhao, Qiang
    Yang, Tao
    Zuo, Jinglin
    Huang, Wei
    DALTON TRANSACTIONS, 2013, 42 (16) : 5718 - 5723
  • [50] Kinetic separation of propylene over propane in a microporous metal-organic framework
    Li, Libo
    Lin, Rui-Biao
    Wang, Xiaoqing
    Zhou, Wei
    Jia, Litao
    Li, Jinping
    Chen, Banglin
    CHEMICAL ENGINEERING JOURNAL, 2018, 354 : 977 - 982
12345