Dichlorocarbene addition to allyl phenyl ether under phase-transfer catalysis conditions - A kinetic study

被引：23

作者：

Rajendran, Venugopal ^{[1
]}

Wang, Maw-Ling ^{[2
]}

机构：

[1] Pachaiyappas Coll Men, Dept Chem, Kanchipuram 631501, Tamil Nadu, India

[2] Hung Kuang Univ, Dept Environm Chem, Shalu, Taichung County, Taiwan

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 288卷 / 1-2期

关键词：

reaction kinetics; phase-transfer catalysis; dichlorocarbene; allyl phenyl ether; dichlorocyclopropanation;

D O I：

10.1016/j.molcata.2008.03.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of dichlorocarbene addition to allyl phenyl ether have been studied under phase-transfer catalytic conditions using aqueous sodium hydroxide as the base and benzyltriethylammonium bromide as a phase-transfer catalyst. The reaction was carried out at 35 degrees C under pseudo-first-order conditions by keeping aqueous sodium hydroxide and chloroform in excess and was monitored by GC. The effect of various experimental parameters on the rate of the reaction has been studied and based on the results obtained, a suitable mechanism is proposed. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：23 / 27

页数：5

共 50 条

[31] ELECTROCHEMICAL STUDY OF PHASE-TRANSFER CATALYSIS REACTIONS - THE WILLIAMSON ETHER SYNTHESIS
TAN, SN
DRYFE, RA
GIRAULT, HH
HELVETICA CHIMICA ACTA, 1994, 77 (01) : 231 - 242
[32] Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis
Pawliczek, Martin
Hashimoto, Takuya
Maruoka, Keiji
CHEMICAL SCIENCE, 2018, 9 (05) : 1231 - 1235
[33] ALLYLATION OF ACETANILIDE BY ALLYL ACETATE UNDER METAL-COMPLEX CATALYSIS COMBINED WITH PHASE-TRANSFER CATALYSIS
LEBEDEV, SA
LEONOVA, YP
BERESTOVA, SS
PETROV, ES
ZHURNAL ORGANICHESKOI KHIMII, 1988, 24 (05): : 1112 - 1113
[34] SYNTHESIS OF 3-CYCLOPROPYL-5-(2'-HYDROXY PHENYL)PYRAZOLES UNDER PHASE-TRANSFER CATALYSIS CONDITIONS
RAO, DM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 173 - ORGN
[35] APPLICATIONS OF PHASE-TRANSFER CATALYSIS .1. NEW VARIANT OF DICHLOROCARBENE PREPARATION
DEHMLOW, EV
TETRAHEDRON LETTERS, 1976, (02) : 91 - 94
[36] Synthesis of 2-akylisoflavones under phase-transfer catalysis conditions
Dai DeMing
Weng LingLing
JOURNAL OF CHEMICAL RESEARCH, 2007, (10) : 572 - 573
[37] CHLORINATIONS WITH CARBON-TETRACHLORIDE UNDER CONDITIONS OF PHASE-TRANSFER CATALYSIS
LAURITZEN, SE
ROMMING, C
SKATTEBOL, L
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1981, 35 (04): : 263 - 268
[38] THE REACTION OF DIMETHYL DISULFIDE WITH PHENYLACETYLENE UNDER PHASE-TRANSFER CATALYSIS CONDITIONS
AMOSOVA, SV
POTAPOV, VA
LASITSA, NA
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (05): : 1069 - 1070
[39] A practical synthesis of benzocrown ethers under phase-transfer catalysis conditions
Bogaschenko, Tatyana
Basok, Stepan
Kulygina, Catherine
Lyapunov, Alexander
Lukyanenko, Nikolay
Synthesis, 2002, (15) : 2266 - 2270
[40] Rapid and Convenient Thioester Synthesis Under Phase-Transfer Catalysis Conditions
Simion, Cristian
Hashimoto, Iwao
Mitoma, Yoshiharu
Simion, Alina Marieta
Egashira, Naoyoshi
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (12) : 2480 - 2488

← 1 2 3 4 5 →