The Diels-Alder reaction using a vinyl sulfoxide activated by the participation of a neighboring epoxide group

被引：0
|
作者：
Abe, H [1 ]
Tsuchida, D
Kashino, S
Takeuchi, Y
Harayama, T
机构：
[1] Okayama Univ, Fac Pharmaceut Sci, Okayama 7008530, Japan
[2] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 1999年 / 47卷 / 06期
关键词：
Diels-Alder reaction; vinyl sulfoxide; epoxide; neighboring participation; sulfonium salt;
D O I：
暂无
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
A vinyl sulfoxide, which is considered to be a moderately reactive dienophile, could be activated by neighboring participation of an epoxide group. The Diels-Alder reaction of ortho-epoxyphenyl vinyl sulfoxide with cyclopentadiene in the presence of Yb(OTf)(3) proceeded smoothly even at room temperature to afford the epoxy-opened cycloadducts with moderate stereoselectivity.
引用
收藏
页码：833 / 837
页数：5
相关论文
共 50 条
12345