Study of the electronic structure of polymeric cubane cluster compounds Mo4S4Cl4, GaMo4S8, and Ga4Mo4S4Te4 by X-ray electron and emission spectroscopy

被引：2

作者：

Khudorozhko, GF

Asanov, IP

Mazalov, LN

Kravtsova, EA

Parygina, GK

Fedorov, VE

Mironov, YV

机构：

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1997年 / 83卷 / 2-3期

关键词：

electronic structure; group theory analysis; photoelectron spectra; polymeric cubane cluster; x-ray electron spectroscopy; x-ray emission spectroscopy;

D O I：

10.1016/S0368-2048(96)03078-2

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The electronic structure of polymeric cubane cluster compounds Mo4S4Cl4, GaMo4S8, and GaMo4S4Te4 has been studied by X-ray electron and emission spectroscopy, The results of the investigation revealed that the higher occupied levels (MoMo bonds) contain mainly the d-orbitals of metal atoms and include also an appreciable contribution from the ligand orbitals. Upon substitution of Cl by S or Te the covalency of the metal-bridging ligand bonds is increased. Group theory analysis of orbital interactions in Mo4S4Cl4 has been performed. A comparison of the results of this analysis and the experimental data shows that the M-S and M-X bonds are many-centered in nature. Based on the experimental data obtained a qualitative model of the electronic structure of the valence band has been proposed. (C) 1997 Elsevier Science B.V.

引用

页码：129 / 136

页数：8

共 50 条

[31] STUDYING THE ELECTRONIC STRUCTURE OF TRINUCLEAR MOLYBDENUM CLUSTER SULFIDES WITH {Mo3S4} AND {Mo3S7} CORES BY X-RAY SPECTROSCOPY
Fedorenko, A. D.
Semushkina, G., I
Peregudova, N. N.
Lavrukhina, S. A.
Gushchin, A. L.
Fomenko, Ya S.
Sokolov, M. N.
Gusel'nikov, A., V
Kalinkin, A., V
Nikolenko, A. D.
Ivlyushkin, D., V
Zavertkin, P. S.
Mazalov, L. N.
JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (06) : 853 - 864
[32] Skyrmionic order and magnetically induced polarization change in lacunar spinel compounds GaV4S8 and GaMo4S8: Comparative theoretical study
Nikolaev, S. A.
Solovyev, I., V
PHYSICAL REVIEW B, 2020, 102 (01)
[33] STUDYING THE ELECTRONIC STRUCTURE OF TRINUCLEAR MOLYBDENUM CLUSTER SULFIDES WITH {Mo3S4} AND {Mo3S7} CORES BY X-RAY SPECTROSCOPY
A. D. Fedorenko
G. I. Semushkina
N. N. Peregudova
S. A. Lavrukhina
A. L. Gushchin
Ya. S. Fomenko
M. N. Sokolov
A. V. Gusel′nikov
A. V. Kalinkin
A. D. Nikolenko
D. V. Ivlyushkin
P. S. Zavertkin
L. N. Mazalov
Journal of Structural Chemistry, 2021, 62 : 853 - 864
[34] V4S4 cubane-like cluster:: synthesis, structure and properties of (Et4N) [V4S4(C4H8dtc)6]
Zhu, HP
Liu, QT
Chen, CN
Wu, DX
INORGANICA CHIMICA ACTA, 2000, 306 (02) : 131 - 136
[35] ELECTRONIC-STRUCTURE OF AS4S4 AND AS4SE4
LIANG, KS
SALANECK, WR
PATON, A
LIPARI, NO
BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1975, 20 (03): : 402 - 402
[36] SYNTHESES AND CHARACTERIZATION OF CUBANE-TYPE CLUSTERS, [MO4S4(EDTA)2]N- (N = 2-4), [MO4S4(H2O)12]N+ (N = 4-6) AND [MO4S4(NH3)12]4+ - X-RAY STRUCTURES OF NA2[MO4S4(EDTA)2].6H2O, CA1.5[MO4S4(EDTA)2].13H2O, MG2[MO4S4(EDTA)2].20H2O, [MO4S4(H2O)12](CH3C6H4SO3)5.14H2O AND [MO4S4(NH3)12]CL4.7H2O
SHIBAHARA, T
KUROYA, H
AKASHI, H
MATSUMOTO, K
OOI, S
INORGANICA CHIMICA ACTA, 1993, 212 (1-2) : 251 - 263
[37] Rearrangement of the Mo/Fe/S cluster under the reducing conditions;: Alternative synthesis of MoFe4S6(PEt3)4Cl cluster from [(Cl4-cat)Mo(MeCN)Fe3S4Cl3](Et4N)2
Shin, BK
Han, JH
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2006, 27 (01): : 35 - 36
[38] ELECTRONIC-STRUCTURE AND BONDING IN HETEROMETALLIC CUBANE-TYPE CLUSTERS HAVING AN MO2FE2S4, MO2CO2S4, MO2NI2S4 CORE
HARRIS, S
INORGANIC CHEMISTRY, 1987, 26 (25) : 4278 - 4285
[39] SYNTHESIS AND STRUCTURE OF A PYRIDINE COMPLEX OF TRINUCLEAR MOLYBDENUM CLUSTER [MO3S4CL4(PY)(5)]
MIZUTANI, J
IMOTO, H
SAITO, T
CHEMISTRY LETTERS, 1994, (11) : 2117 - 2118
[40] Collision-induced dissociation of [4Fe-4S] cubane cluster complexes:: [Fe4S4Cl4-x(SC2H5)x]2-/1- (x=0-4)
Fu, You-Jun
Laskin, Julia
Wang, Lai-Sheng
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2006, 255 : 102 - 110

← 1 2 3 4 5 →