4,5-Dihydroisoxazoles in the synthesis of new metallomesogens

被引：7
|
作者：
Kovganko, VN [1 ]
Kovganko, NN [1 ]
机构：
[1] Byelorussian State Univ, Sevchenko Inst Appl Phys Problems, Minsk 220064, BELARUS
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 42卷 / 03期
关键词：
D O I：
10.1134/S1070428006030158
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new approach to the synthesis of metallomesogens containing beta-enaminoketone fragments as chelating moieties was developed. The corresponding enaminoketone was synthesized by the oxidation of 3-(4'-butoxybiphenyl-4-yl)-5-pentyl-4,5-dihydroisoxazole to 3-(4'-butoxybiphenyl-4-yl)-5-pentyl-4,5-isoxazole, followed by opening of the isoxazole ring. The reaction of the enaminoketone with copper(II) and nickel(H) acetates gave the target mesogenic metal complexes.
引用
收藏
页码：430 / 434
页数：5
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