4,5-Dihydroisoxazoles in the synthesis of new metallomesogens

被引：7
|
作者：
Kovganko, VN [1 ]
Kovganko, NN [1 ]
机构：
[1] Byelorussian State Univ, Sevchenko Inst Appl Phys Problems, Minsk 220064, BELARUS
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 42卷 / 03期
关键词：
D O I：
10.1134/S1070428006030158
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new approach to the synthesis of metallomesogens containing beta-enaminoketone fragments as chelating moieties was developed. The corresponding enaminoketone was synthesized by the oxidation of 3-(4'-butoxybiphenyl-4-yl)-5-pentyl-4,5-dihydroisoxazole to 3-(4'-butoxybiphenyl-4-yl)-5-pentyl-4,5-isoxazole, followed by opening of the isoxazole ring. The reaction of the enaminoketone with copper(II) and nickel(H) acetates gave the target mesogenic metal complexes.
引用
收藏
页码：430 / 434
页数：5
相关论文
共 50 条
  • [1] 4,5-Dihydroisoxazoles in the synthesis of new metallomesogens
    V. N. Kovganko
    N. N. Kovganko
    Russian Journal of Organic Chemistry, 2006, 42 : 430 - 434
  • [2] Synthesis of 4,5-dihydroisoxazoles bearing phosphonate moiety
    Yuan, CY
    Li, CZ
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 111 (1-4): : 834 - 834
  • [3] PUMMERER REACTION OF 3-SULPHINYLMETHYL-4,5-DIHYDROISOXAZOLES - A NEW SYNTHESIS OF PROTECTED 3-FORMYL-4,5-DIHYDROISOXAZOLES
    COZZI, F
    GOBBI, C
    RAIMONDI, L
    RESTELLI, A
    GAZZETTA CHIMICA ITALIANA, 1986, 116 (12): : 717 - 719
  • [4] Synthesis of 4,5-dihydroisoxazoles from arylcyclopropanes and nitrosyl chloride
    Bondarenko, OB
    Gavrilova, AY
    Saginova, LG
    Zyk, NV
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 39 (07) : 1021 - 1024
  • [5] 4,5-DIHYDROISOXAZOLES .4. 4 AND 5-PHENYLTHIO-4,5-DIHYDROISOXAZOLES AND THEIR BEHAVIOR WITH PERFORMIC ACID
    BIANCHETTI, G
    POCAR, D
    TORRICELLI, C
    ARLANDINI, E
    GIOIA, B
    GAZZETTA CHIMICA ITALIANA, 1981, 111 (7-8): : 315 - 323
  • [6] Synthesis of 4,5-Dihydroisoxazoles from Arylcyclopropanes and Nitrosyl Chloride
    O. B. Bondarenko
    A. Yu. Gavrilova
    L. G. Saginova
    N. V. Zyk
    Russian Journal of Organic Chemistry, 2003, 39 : 1021 - 1024
  • [7] Synthesis of new 4,5-dihydroisoxazoles with potential anti-inflammatory activity.
    Molina, CT
    de Aguiar, AP
    HETEROCYCLIC COMMUNICATIONS, 2003, 9 (05) : 535 - 538
  • [8] Microbial biotransformation of the substituted 4,5-dihydroisoxazoles
    Zadrozna, I
    Kurkowska, J
    SPECTROSCOPY OF BIOLOGICAL MOLECULES: MODERN TRENDS, 1997, : 493 - 494
  • [9] 4,5-Dihydroisoxazoles - Testing of antimicrobial activity
    Zadrozna, I
    Kurkowska, J
    Kruszewska, H
    Makuch, I
    FARMACO, 2000, 55 (6-7): : 499 - 501
  • [10] Synthesis of 4,5-dihydroisoxazoles from N-nitroso-4,5-dihydropyrazoles
    Molchanov, AP
    Stepakov, AV
    Kostikov, RR
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 40 (10) : 1512 - 1517
12345